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dc.contributor.authorGe, Xiao
dc.contributor.authorMa, Yue
dc.contributor.authorSong, Xiangyang
dc.contributor.authorWang, Guozhong
dc.contributor.authorZhang, Haimin
dc.contributor.authorZhang, Yunxia
dc.contributor.authorZhao, Huijun
dc.date.accessioned2017-06-23T00:28:08Z
dc.date.available2017-06-23T00:28:08Z
dc.date.issued2017
dc.identifier.issn1944-8244
dc.identifier.doi10.1021/acsami.7b01275
dc.identifier.urihttp://hdl.handle.net/10072/340726
dc.description.abstractArsenic pollution in waters has become a worldwide issue, constituting a severe hazard to whole ecosystems and public health worldwide. Accordingly, it is highly desirable to design high-performance adsorbents for arsenic decontamination. Herein, a feasible strategy is developed for in situ growth of β-FeOOH nanorods (NRs) on a three-dimensional (3D) carbon foam (CF) skeleton via a simple calcination process and subsequent hydrothermal treatment. The as-fabricated 3D β-FeOOH NRs/CF monolith can be innovatively utilized for arsenic remediation from contaminated aqueous systems, accompanied by remarkably high uptake capacity of 103.4 mg/g for arsenite and 172.9 mg/g for arsenate. The superior arsenic uptake performance can be ascribed to abundant active sites and hydroxyl functional groups available as well as efficient mass transfer associated with interconnected hierarchical porous networks. In addition, the as-obtained material exhibits exceptional sorption selectivity toward arsenic over other coexisting anions at high levels, which can be ascribed to strong affinity between active sites and arsenic. More importantly, the free-standing 3D porous monolith not only makes it easy for separation and collection after treatment but also efficiently prevents the undesirable potential release of nanoparticles into aquatic environments while maintaining the outstanding properties of nanometer-scale building blocks. Furthermore, the monolith absorbent is able to be effectively regenerated and reused for five cycles with negligible decrease in arsenic removal. In view of extremely high adsorption capacities, preferable sorption selectivity, satisfactory recyclability, as well as facile separation nature, the obtained 3D β-FeOOH NRs/CF monolith holds a great potential for arsenic decontamination in practical applications.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofpagefrom13480
dc.relation.ispartofpageto13490
dc.relation.ispartofissue15
dc.relation.ispartofjournalACS Applied Materials and Interfaces
dc.relation.ispartofvolume9
dc.subject.fieldofresearchMacromolecular and Materials Chemistry not elsewhere classified
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchcode030399
dc.subject.fieldofresearchcode03
dc.subject.fieldofresearchcode09
dc.titleß-FeOOH Nanorods/Carbon Foam-Based Hierarchically Porous Monolith for Highly Effective Arsenic Removal
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Huijun
gro.griffith.authorZhang, Haimin


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