Racemic 6-exo-hydroxybicyclo[2.2.1]heptane-2-exo-carboxlyic acid

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Author(s)
Smith, Graham
C. Bott, Raymond
Jenkins, Ian
Wermuth, Urs
Year published
2001
Metadata
Show full item recordAbstract
The crystal structure of the title cage hydroxy acid, C8H12O3, has confirmed the exo configuration for both the carboxyl� acid and hydroxy substituents, as previously determined from chemical and 13C NMR evidence. Both the carboxyl� acid and the hydroxy O atoms are involved in intermolecular hydrogen-bonding interactions, giving a centrosymmetric 12-membered cyclic ring system which extends via hydrogen bonding into an infinite two-dimensional network.The crystal structure of the title cage hydroxy acid, C8H12O3, has confirmed the exo configuration for both the carboxyl� acid and hydroxy substituents, as previously determined from chemical and 13C NMR evidence. Both the carboxyl� acid and the hydroxy O atoms are involved in intermolecular hydrogen-bonding interactions, giving a centrosymmetric 12-membered cyclic ring system which extends via hydrogen bonding into an infinite two-dimensional network.
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Journal Title
ACTA Crystallographica Section E - Structure Reports Online
Volume
57
Copyright Statement
© The Author(s) 2001. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Subject
Chemical Sciences