dc.contributor.author | Batista, AA | |
dc.contributor.author | Santiago, MO | |
dc.contributor.author | Donnici, CL | |
dc.contributor.author | Moreira, IS | |
dc.contributor.author | Healy, PC | |
dc.contributor.author | Berners-Price, SJ | |
dc.contributor.author | Queiroz, SL | |
dc.date.accessioned | 2017-05-03T13:33:36Z | |
dc.date.available | 2017-05-03T13:33:36Z | |
dc.date.issued | 2001 | |
dc.date.modified | 2009-08-25T03:46:05Z | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.doi | 10.1016/S0277-5387(01)00744-6 | |
dc.identifier.uri | http://hdl.handle.net/10072/3534 | |
dc.description.abstract | A series of RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N-N) complexes were synthesized from RuCl2(PPh3)3, (N)2=pyridine (py), 4-(N,N-dimethylamino)pyridine (4-dmNpy), 4-tert-butylpyridine (4-tBu-py), 4-methylpyridine (4-Mepy), 4-vinylpyridine (4-Vpy), 4-phenylpyridine (4-Phpy), isonicotinamide (4-CONH2py), 4-cyanopyridine (4-CNpy) N-N=1,10-phenanthroline (phen), 2,2'-bipyridine (bipy), 2,2'-bipyridine-4,4'-dimethoxy (MeO-bipy), 2,2'-bipyridine-4,4'-dimethyl (Me-bipy), 2,2'-bipyridine-4,4'-dithiomethyl (MeS-bipy), 2,2'-bipyridine-4,4'-dichloro (Cl-bipy) and 2,2'-bipyridine-4,4'-dinitro (NO2-bipy). The complexes were characterized by elemental analysis, cyclic voltammetry and UV-Vis, NMR and IR spectroscopies. The structure of the RuCl2(PPh3)2(phen) was established by single crystal X-ray crystallography. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Pergamon | |
dc.publisher.place | UK | |
dc.relation.ispartofpagefrom | 2123 | |
dc.relation.ispartofpageto | 2128 | |
dc.relation.ispartofjournal | Polyhedron | |
dc.relation.ispartofvolume | 20 | |
dc.subject.fieldofresearch | Inorganic chemistry | |
dc.subject.fieldofresearch | Physical chemistry | |
dc.subject.fieldofresearch | Other chemical sciences | |
dc.subject.fieldofresearch | Macromolecular and materials chemistry | |
dc.subject.fieldofresearchcode | 3402 | |
dc.subject.fieldofresearchcode | 3406 | |
dc.subject.fieldofresearchcode | 3499 | |
dc.subject.fieldofresearchcode | 3403 | |
dc.title | Electrochemical and spectroscopic studies on RuCl(PPh3)2(N)2 and RuCl2(PPh3)2((N-N) | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.rights.copyright | | |
gro.date.issued | 2001 | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |
gro.griffith.author | Berners-Price, Sue J. | |