• myGriffith
    • Staff portal
    • Contact Us⌄
      • Future student enquiries 1800 677 728
      • Current student enquiries 1800 154 055
      • International enquiries +61 7 3735 6425
      • General enquiries 07 3735 7111
      • Online enquiries
      • Staff phonebook
    View Item 
    •   Home
    • Griffith Research Online
    • Journal articles
    • View Item
    • Home
    • Griffith Research Online
    • Journal articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

  • All of Griffith Research Online
    • Communities & Collections
    • Authors
    • By Issue Date
    • Titles
  • This Collection
    • Authors
    • By Issue Date
    • Titles
  • Statistics

  • Most Popular Items
  • Statistics by Country
  • Most Popular Authors
  • Support

  • Contact us
  • FAQs
  • Admin login

  • Login
  • Racemic 7-oxabicyclo[2.2.1]heptane-5-exo-iodo-6-endo-hydroxy-2-endo-carboxylic acid-y-lactone

    Thumbnail
    View/Open
    18598_1.pdf (141.1Kb)
    Author(s)
    Smith, Graham
    C. Bott, Raymond
    Jenkins, Ian
    Wermuth, Urs
    Griffith University Author(s)
    Jenkins, Ian D.
    Wermuth, Urs D.
    Year published
    2001
    Metadata
    Show full item record
    Abstract
    The crystal structure of the -lactone of racemic 7-oxabicyclo[2.2.1]heptane-5-exo-iodo-6-endo-hydroxy-2-endo-carboxylic acid has confirmed the position of the lactone bridge as 2-6 and the exo-iodo substituent configuration as previously proposed from chemical and 13C NMR evidence. The iodo substituent is also involved in a short non-bonding intermolecular interaction [IO 3.289 (5) ŝ with the non-bridging lactone oxygen giving polymeric chains which link weakly hydrogen-bonded (C-HO) centrosymmetric dimer units.The crystal structure of the -lactone of racemic 7-oxabicyclo[2.2.1]heptane-5-exo-iodo-6-endo-hydroxy-2-endo-carboxylic acid has confirmed the position of the lactone bridge as 2-6 and the exo-iodo substituent configuration as previously proposed from chemical and 13C NMR evidence. The iodo substituent is also involved in a short non-bonding intermolecular interaction [IO 3.289 (5) ŝ with the non-bridging lactone oxygen giving polymeric chains which link weakly hydrogen-bonded (C-HO) centrosymmetric dimer units.
    View less >
    Journal Title
    ACTA Crystallographica Section E - Structure Reports Online
    Volume
    57
    DOI
    https://doi.org/10.1107/S1600536801012661
    Copyright Statement
    © The Author(s) 2001. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
    Subject
    Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/3564
    Collection
    • Journal articles

    Footer

    Disclaimer

    • Privacy policy
    • Copyright matters
    • CRICOS Provider - 00233E

    Tagline

    • Gold Coast
    • Logan
    • Brisbane - Queensland, Australia
    First Peoples of Australia
    • Aboriginal
    • Torres Strait Islander