Carbene induced rearrangement products from two furoquinolinone scaffolds
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Novel double CH-insertion and rearrangement products (5, 6, and 7) were isolated from treatment of 1 or 2 with dimethyl diazomalonate (3) under dirhodiumtetrakis mediated carbenoid chemistry conditions. A new possible reaction pathway is suggested and discussed. Also other diazo compounds were tested.
Journal of Heterocyclic Chemistry
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Organic Chemical Synthesis