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  • Free nitrous acid pre-treatment of waste activated sludge enhances volatile solids destruction and improves sludge dewaterability in continuous anaerobic digestion

    Author(s)
    Wei, Wei
    Wang, Qilin
    Zhang, Liguo
    Laloo, Andrew
    Duan, Haoran
    Batstone, Damien J
    Yuan, Zhiguo
    Griffith University Author(s)
    Wang, Qilin
    Year published
    2018
    Metadata
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    Abstract
    Previous work has demonstrated that pre-treatment of waste activated sludge (WAS) with free nitrous acid (FNA i.e. HNO2) enhances the biodegradability of WAS, identified by a 20–50% increase in specific methane production in biochemical methane potential (BMP) tests. This suggests that FNA pre-treatment would enhance the destruction of volatile solids (VS) in an anaerobic sludge digester, and reduce overall sludge disposal costs, provided that the dewaterability of the digested sludge is not negatively affected. This study experimentally evaluates the impact of FNA pre-treatment on the VS destruction in anaerobic sludge ...
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    Previous work has demonstrated that pre-treatment of waste activated sludge (WAS) with free nitrous acid (FNA i.e. HNO2) enhances the biodegradability of WAS, identified by a 20–50% increase in specific methane production in biochemical methane potential (BMP) tests. This suggests that FNA pre-treatment would enhance the destruction of volatile solids (VS) in an anaerobic sludge digester, and reduce overall sludge disposal costs, provided that the dewaterability of the digested sludge is not negatively affected. This study experimentally evaluates the impact of FNA pre-treatment on the VS destruction in anaerobic sludge digestion and on the dewaterability of digested sludge, using continuously operated bench-scale anaerobic digesters. Pre-treatment of full-scale WAS for 24 h at an FNA concentration of 1.8 mg NN/L enhanced VS destruction by 17 ± 1% (from 29.2 ± 0.9% to 34.2 ± 1.1%) and increased dewaterability (centrifuge test) from 12.4 ± 0.4% to 14.1 ± 0.4%. Supporting the VS destruction data, methane production increased by 16 ± 1%. Biochemical methane potential tests indicated that the final digestate stability was also improved with a lower potential from FNA treated digestate. Further, a 2.1 ± 0.2 log improvement in pathogen reduction was also achieved. With inorganic solids representing 15–22% of the full-scale WAS used, FNA pre-treatment resulted in a 16–17% reduction in the volume of dewatered sludge for final disposal. This results in significantly reduced costs as assessed by economic analysis.
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    Journal Title
    Water Research
    Volume
    130
    DOI
    https://doi.org/10.1016/j.watres.2017.11.050
    Subject
    Environmentally sustainable engineering
    Global and planetary environmental engineering
    Publication URI
    http://hdl.handle.net/10072/368744
    Collection
    • Journal articles

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