The key surface species and oxygen vacancies in MnOx(0.4)-CeO2 toward repeated soot oxidation
Author(s)
He, Hui
Lin, Xueting
Li, Shujun
Wu, Zeng
Gao, Jingheng
Wu, Junliang
Wen, William
Ye, Daiqi
Fu, Mingli
Griffith University Author(s)
Year published
2018
Metadata
Show full item recordAbstract
Surface species and oxygen vacancies were studied in MnOx(0.4)-CeO2 toward repeated soot oxidation. MnOx(0.4)-CeO2 catalysts prepared by the citric acid complex method were repeatedly used in a 10% O2/Ar gas flow and showed favorable activity and satisfactory durability toward soot oxidation. X-ray diffraction (XRD), N2 adsorption/desorption, Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS) and in situ visible/UV Raman characterization methods were utilized to investigate the structural features of fresh and reused catalysts. The irreversible conversion of high valence manganese species as well ...
View more >Surface species and oxygen vacancies were studied in MnOx(0.4)-CeO2 toward repeated soot oxidation. MnOx(0.4)-CeO2 catalysts prepared by the citric acid complex method were repeatedly used in a 10% O2/Ar gas flow and showed favorable activity and satisfactory durability toward soot oxidation. X-ray diffraction (XRD), N2 adsorption/desorption, Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS) and in situ visible/UV Raman characterization methods were utilized to investigate the structural features of fresh and reused catalysts. The irreversible conversion of high valence manganese species as well as the reduction of Frenkel-type oxygen vacancies and lattice oxygen could be clearly observed in the reused samples, which were associated with the slight deactivation. Spectators and participators were two existing forms of Frenkel-type oxygen vacancies. It was noteworthy that the participators almost fully regenerated after each reaction cycle, which ensured the ability to activate Olatt in repeated soot oxidation process. Therefore, the catalysts maintained favorable activity and satisfactory durability, which was mainly because the relatively stable level of participators.
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View more >Surface species and oxygen vacancies were studied in MnOx(0.4)-CeO2 toward repeated soot oxidation. MnOx(0.4)-CeO2 catalysts prepared by the citric acid complex method were repeatedly used in a 10% O2/Ar gas flow and showed favorable activity and satisfactory durability toward soot oxidation. X-ray diffraction (XRD), N2 adsorption/desorption, Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS) and in situ visible/UV Raman characterization methods were utilized to investigate the structural features of fresh and reused catalysts. The irreversible conversion of high valence manganese species as well as the reduction of Frenkel-type oxygen vacancies and lattice oxygen could be clearly observed in the reused samples, which were associated with the slight deactivation. Spectators and participators were two existing forms of Frenkel-type oxygen vacancies. It was noteworthy that the participators almost fully regenerated after each reaction cycle, which ensured the ability to activate Olatt in repeated soot oxidation process. Therefore, the catalysts maintained favorable activity and satisfactory durability, which was mainly because the relatively stable level of participators.
View less >
Journal Title
Applied Catalysis B: Environmental
Volume
223
Subject
Physical chemistry
Chemical engineering
Environmental engineering
Environmental engineering not elsewhere classified