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dc.contributor.authorZu, Meng Yang
dc.contributor.authorLiu, Peng Fei
dc.contributor.authorWang, Chongwu
dc.contributor.authorWang, Yun
dc.contributor.authorZheng, Li Rong
dc.contributor.authorZhang, Bo
dc.contributor.authorZhao, Huijun
dc.contributor.authorYang, Hua Gui
dc.date.accessioned2019-06-19T13:07:42Z
dc.date.available2019-06-19T13:07:42Z
dc.date.issued2018
dc.identifier.issn2380-8195
dc.identifier.doi10.1021/acsenergylett.7b00990
dc.identifier.urihttp://hdl.handle.net/10072/378714
dc.description.abstractCheap, efficient, and stable hydrogen evolution reaction (HER) electrocatalysts have long been pursued, owing to their scientific and technological importance. Currently, platinum has been regarded as the benchmarked HER electrocatalyst. Unfortunately, the low abundance and high cost impede its industrial applications. Here, we synthesize bimetallic carbide Mo6Ni6C grown on nickel foam as a HER catalyst, delivering a low overpotential of −51 mV at −10 mA cm–2 in 0.5 M H2SO4 for more than 200 h, which is among the best reported benchmarked HER catalysts in acid to date. On the basis of experimental observations and theoretical modeling, we ascribe the good activity to the proper Gibbs free energy of adsorbed hydrogen (ΔG(H*)) for the carbon active sites and attribute the stability to the corrosion-stable Mo–Mo bonds in the crystal structure. This work demonstrates the possibility for Mo6Ni6C to be one of the best candidates for HER electrocatalysts in the large-scale electrolysis industry.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.relation.ispartofpagefrom78
dc.relation.ispartofpageto84
dc.relation.ispartofissue1
dc.relation.ispartofjournalACS Energy Letters
dc.relation.ispartofvolume3
dc.subject.fieldofresearchEnvironmental Sciences not elsewhere classified
dc.subject.fieldofresearchcode059999
dc.titleBimetallic Carbide as a Stable Hydrogen Evolution Catalyst in Harsh Acidic Water
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Huijun
gro.griffith.authorWang, Yun
gro.griffith.authorYang, Huagui


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