(η5-pentamethylcyclopentadienyl)(η6-4-phenylbutan-2-one)ruthenium(II) tetraphenylborate

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Author(s)
Loughrey, Bradley T
Williams, Michael L
Healy, Peter C
Griffith University Author(s)
Year published
2010
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Abstract
The title compound, [Ru(C10H15)(C10H12O)][B(C6H5)4], crystallizes as discrete (5-pentamethylcyclopentadienyl)Ru(6-4-phenylbutan-2-one)]+ cations and [BPh4]- anions. In the cation, the non-H atoms of the butan-2-one group are approximately planar (r.m.s. deviation = 0.056 ũ and lie nearly perpendicular to the plane of the phenyl ring with a dihedral angle between the two planes of 69.3 (1)஠No significant C-HO interactions are observed between the methyl and phenyl H atoms and the carbonyl O atom.
Journal Title
Acta Crystallographica. Section E: Structure Reports Online
Volume
E66
Issue
12
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© The Author(s) 2010. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical sciences
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