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dc.contributor.authorZhao, Kun
dc.contributor.authorZhao, Shenlong
dc.contributor.authorGao, Chao
dc.contributor.authorQi, Jian
dc.contributor.authorYin, Huajie
dc.contributor.authorWei, Ding
dc.contributor.authorMideksa, Megasia Feyissa
dc.contributor.authorWang, Xiaoli
dc.contributor.authorGao, Yan
dc.contributor.authorTang, Zhiyong
dc.contributor.authorYu, Ranbo
dc.date.accessioned2019-06-12T12:33:16Z
dc.date.available2019-06-12T12:33:16Z
dc.date.issued2018
dc.identifier.issn1613-6810
dc.identifier.doi10.1002/smll.201800762
dc.identifier.urihttp://hdl.handle.net/10072/382165
dc.description.abstractCO2 conversion into value‐added chemical fuels driven by solar energy is an intriguing approach to address the current and future demand of energy supply. Currently, most reported surface‐sensitized heterogeneous photocatalysts present poor activity and selectivity under visible light irradiation. Here, photosensitized porous metallic and magnetic 1200 CoC composites (PMMCoCC‐1200) are coupled with a [Ru(bpy)3]Cl2 photosensitizer to efficiently reduce CO2 under visible‐light irradiation in a selective and sustainable way. As a result, the CO production reaches a high yield of 1258.30 µL with selectivity of 64.21% in 6 h, superior to most reported heterogeneous photocatalysts. Systematic investigation demonstrates that the central metal cobalt is the active site for activating the adsorbed CO2 molecules and the surficial graphite carbon coating on cobalt metal is crucial for transferring the electrons from the triplet metal‐to‐ligand charge transfer of the photosensitizer Ru(bpy)32+, which gives rise to significant enhancement for CO2 reduction efficiency. The fast electron injection from the excited Ru(bpy)32+ to PMMCoCC‐1200 and the slow backward charge recombination result in a long‐lived, charge‐separated state for CO2 reduction. More impressively, the long‐time stability and easy magnetic recycling ability of this metallic photocatalyst offer more benefits to the photocatalytic field.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherJohn Wiley & Sons
dc.publisher.placeGermany
dc.relation.ispartofchapter1800762
dc.relation.ispartofpagefrom1
dc.relation.ispartofpageto8
dc.relation.ispartofissue33
dc.relation.ispartofjournalSmall
dc.relation.ispartofvolume14
dc.subject.fieldofresearchEnvironmental Sciences not elsewhere classified
dc.subject.fieldofresearchcode059999
dc.subject.keywordsPhotocatalytic CO2 reduction
dc.subject.keywordsMetallic composites
dc.subject.keywordsMagnetic recyclable materials
dc.titleMetallic Cobalt-Carbon Composite as Recyclable and Robust Magnetic Photocatalyst for Efficient CO2 Reduction
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.facultyGriffith Sciences, Centre for Clean Environment and Energy
gro.hasfulltextNo Full Text
gro.griffith.authorTang, Zhiyong
gro.griffith.authorYin, Huajie
gro.griffith.authorZhao, Kun


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