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dc.contributor.authorGong, Wanbing
dc.contributor.authorChen, Chun
dc.contributor.authorZhang, Haimin
dc.contributor.authorWang, Guozhong
dc.contributor.authorZhao, Huijun
dc.date.accessioned2019-06-07T01:44:29Z
dc.date.available2019-06-07T01:44:29Z
dc.date.issued2018
dc.identifier.issn2044-4753
dc.identifier.doi10.1039/C8CY01488D
dc.identifier.urihttp://hdl.handle.net/10072/382254
dc.description.abstractN-Doped carbon nanotube-encapsulated metal nanoparticles are of great interest in heterogeneous catalysis owing to their improved mass transfer ability and superior stability. Herein, a facile one-pot pyrolysis approach using melamine as the carbon and nitrogen source was developed to fabricate metal nanoparticles embedded in bamboo-like N-doped carbon nanotubes (named as Co@NCNTs-600-800 and Ni@NCNTs-600-800). The optimized Co@NCNTs-600-800 catalyst exhibited outstanding activity in furfural (FAL) selective hydrogenation to furfuryl alcohol (FOL) or cyclopentanone (CPO) in aqueous media. High yields of FOL (100%) and CPO (75.3%) were achieved at 80 °C and 140 °C, respectively. Besides, this cobalt catalyst showed very good stability and recyclability during the reaction. The synergistic effect between metallic cobalt and N-doped carbon nanotubes was systematically investigated. In addition, the as-prepared Ni@NCNTs-600-800 catalyst also exhibited remarkable activity. Under optimal conditions (100 °C and 4 MPa H2 pressure), a maximum tetrahydrofurfuryl alcohol (THFOL) yield (99.5%) was obtained in the aqueous-phase hydrogenation of FAL. The research thus highlights new perspectives for non-noble metal-based N-doped carbon nanotube catalysts for biomass transformation.
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherRoyal Society of Chemistry
dc.publisher.placeUnited Kingdom
dc.relation.ispartofpagefrom5506
dc.relation.ispartofpageto5514
dc.relation.ispartofissue21
dc.relation.ispartofjournalCatalysis Science & Technology
dc.relation.ispartofvolume8
dc.subject.fieldofresearchChemical Engineering not elsewhere classified
dc.subject.fieldofresearchcode090499
dc.subject.keywordsNanoparticles
dc.subject.keywordsN-doped carbon nanotubes
dc.subject.keywordsEfficient catalysts
dc.subject.keywordsUnsaturated oxygen compounds
dc.subject.keywordsAqueous phase
dc.titleHighly dispersed Co and Ni nanoparticles encapsulated in N-doped carbon nanotubes as efficient catalysts for the reduction of unsaturated oxygen compounds in aqueous phase
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Huijun
gro.griffith.authorZhang, Haimin


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