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dc.contributor.authorGong, Wanbing
dc.contributor.authorChen, Chun
dc.contributor.authorZhang, Haimin
dc.contributor.authorWang, Guozhong
dc.contributor.authorZhao, Huijun
dc.date.accessioned2019-06-19T13:11:24Z
dc.date.available2019-06-19T13:11:24Z
dc.date.issued2018
dc.identifier.issn2168-0485
dc.identifier.doi10.1021/acssuschemeng.8b03418
dc.identifier.urihttp://hdl.handle.net/10072/382471
dc.description.abstractHerein, we report that highly dispersed copper–cobalt mixed metal/metal oxide nanoparticles embedded into three-dimensional porous carbon were highly catalytic active nanocomposites for transforming bioderived furfural (FAL) to cyclopentanone (CPO) via aqueous-phase hydrogenation/rearrangement. This simple and efficient catalyst was prepared by controlled pyrolysis procedure using glucose as the carbon source at 500 °C under N2 atmosphere. Characterization of the as-prepared CuCo0.8@C-500 catalyst by XRD, STEM, SEM, TEM, and XPS suggested that there was a synergism between copper and cobalt. Under an extremely low H2 pressure (0.5 MPa), 90.2% yield of CPO could be attained at 150 °C. In addition, the sample could be recycled for several times without decrease in catalytic activity. Two critical reaction intermediates of furfuryl alcohol (FOL) and 2-cyclopentenone (2-CPE) were detected in the tandem catalytic process. These results demonstrated that this synthetic strategy represented a simple and effective way for utilization of inexpensive biomass resources to obtain some valuable chemicals.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.relation.ispartofpagefrom14919
dc.relation.ispartofpageto14925
dc.relation.ispartofissue11
dc.relation.ispartofjournalACS Sustainable Chemistry and Engineering
dc.relation.ispartofvolume6
dc.subject.fieldofresearchAnalytical Chemistry not elsewhere classified
dc.subject.fieldofresearchAnalytical Chemistry
dc.subject.fieldofresearchEnvironmental Science and Management
dc.subject.fieldofresearchChemical Engineering
dc.subject.fieldofresearchcode030199
dc.subject.fieldofresearchcode0301
dc.subject.fieldofresearchcode0502
dc.subject.fieldofresearchcode0904
dc.titleIn Situ Synthesis of Highly Dispersed Cu−Co Bimetallic Nanoparticles for Tandem Hydrogenation/Rearrangement of Bioderived Furfural in Aqueous-Phase
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Huijun
gro.griffith.authorZhang, Haimin


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