dc.contributor.author | Batista, AA | |
dc.contributor.author | Queiroz, SL | |
dc.contributor.author | Healy, PC | |
dc.contributor.author | Buckley, RW | |
dc.contributor.author | Boyd, SE | |
dc.contributor.author | Berners-Price, SJ | |
dc.contributor.author | Castellano, EE | |
dc.contributor.author | Ellena, J | |
dc.contributor.editor | Bruce P Dancik | |
dc.date.accessioned | 2017-05-03T13:31:45Z | |
dc.date.available | 2017-05-03T13:31:45Z | |
dc.date.issued | 2001 | |
dc.identifier.issn | 0008-4042 | |
dc.identifier.doi | 10.1139/cjc-79-5-6-1030 | |
dc.identifier.uri | http://hdl.handle.net/10072/3830 | |
dc.description.abstract | The ruthenium(II) complex, [RuCl2(NO)L] (I), (L=[(2-py)2PC2H4PO2(2-py)]-) was obtained from recrystallization of RuCl3NO(d2pype) (d2pype=(2-py)2PC2H4P(2-py)2) in the presence of HNO3, crystallizing in the monoclinic space group P21 (no. 4), with a =8.012(4) Ŭ b=14.454(4) Ŭ c=9.353(3) Ŭ ߽105.77(3)ଠand Z=2. Crystals of the DMSO solvate of the complex (II) were obtained from (CD3)2SO solution, crystallizing in the monoclinic space group P21/c (no.14) with a =9.7080(2) Ŭ b=22.2920(5) Ŭ c=11.5230(3) Ŭ ߽92.0450(10)ଠand Z=4. In both complexes, the geometry about the ruthenium atom is a distorted octahedron mainly as a result of the tridentate [P,N,O]-bonding mode of L. The ? (NO) bands at 1875 cm-1 in both complexes are consistent with the linear disposition of the NO group and the Ru atom as is observed in the X-ray crystal structure (Ru-N1-O1 angle=178.5(4)੮ | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | NRC Research Press | |
dc.publisher.place | Canada | |
dc.relation.ispartofpagefrom | 1030 | |
dc.relation.ispartofpageto | 1035 | |
dc.relation.ispartofissue | 6 | |
dc.relation.ispartofjournal | Canadian Journal of Chemistry | |
dc.relation.ispartofvolume | 79 | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | A novel coordination mode for a pyridylphosphine ligand. X-ray structures of RuCl2(NO)(2-py)2PC2H4P=O,O-(2-py) (I) and RuCl2(NO)(2-py)2PC2H4P=O,O-(2-py).DMSO (II) | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.date.issued | 2015-05-12T02:01:45Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |
gro.griffith.author | Berners-Price, Sue J. | |