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dc.contributor.authorBatista, AA
dc.contributor.authorQueiroz, SL
dc.contributor.authorHealy, PC
dc.contributor.authorBuckley, RW
dc.contributor.authorBoyd, SE
dc.contributor.authorBerners-Price, SJ
dc.contributor.authorCastellano, EE
dc.contributor.authorEllena, J
dc.contributor.editorBruce P Dancik
dc.date.accessioned2017-05-03T13:31:45Z
dc.date.available2017-05-03T13:31:45Z
dc.date.issued2001
dc.identifier.issn0008-4042
dc.identifier.doi10.1139/cjc-79-5-6-1030
dc.identifier.urihttp://hdl.handle.net/10072/3830
dc.description.abstractThe ruthenium(II) complex, [RuCl2(NO)L] (I), (L=[(2-py)2PC2H4PO2(2-py)]-) was obtained from recrystallization of RuCl3NO(d2pype) (d2pype=(2-py)2PC2H4P(2-py)2) in the presence of HNO3, crystallizing in the monoclinic space group P21 (no. 4), with a =8.012(4) Ŭ b=14.454(4) Ŭ c=9.353(3) Ŭ ߽105.77(3)ଠand Z=2. Crystals of the DMSO solvate of the complex (II) were obtained from (CD3)2SO solution, crystallizing in the monoclinic space group P21/c (no.14) with a =9.7080(2) Ŭ b=22.2920(5) Ŭ c=11.5230(3) Ŭ ߽92.0450(10)ଠand Z=4. In both complexes, the geometry about the ruthenium atom is a distorted octahedron mainly as a result of the tridentate [P,N,O]-bonding mode of L. The ? (NO) bands at 1875 cm-1 in both complexes are consistent with the linear disposition of the NO group and the Ru atom as is observed in the X-ray crystal structure (Ru-N1-O1 angle=178.5(4)੮
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherNRC Research Press
dc.publisher.placeCanada
dc.relation.ispartofpagefrom1030
dc.relation.ispartofpageto1035
dc.relation.ispartofissue6
dc.relation.ispartofjournalCanadian Journal of Chemistry
dc.relation.ispartofvolume79
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleA novel coordination mode for a pyridylphosphine ligand. X-ray structures of RuCl2(NO)(2-py)2PC2H4P=O,O-(2-py) (I) and RuCl2(NO)(2-py)2PC2H4P=O,O-(2-py).DMSO (II)
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-12T02:01:45Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.
gro.griffith.authorBerners-Price, Sue J.


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