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dc.contributor.authorBatista, Alziren_US
dc.contributor.authorQueiroz, Saleteen_US
dc.contributor.authorHealy, Peteren_US
dc.contributor.authorBuckley, Robbieen_US
dc.contributor.authorBoyd, Sueen_US
dc.contributor.authorBerners-Price, Sueen_US
dc.contributor.authorCastellano, Eduardoen_US
dc.contributor.authorEllena, Javieren_US
dc.contributor.editorBruce P Danciken_US
dc.date.accessioned2017-04-24T10:40:46Z
dc.date.available2017-04-24T10:40:46Z
dc.date.issued2001en_US
dc.identifier.issn00084042en_US
dc.identifier.doi10.1139/cjc-79-5-6-1030en_US
dc.identifier.urihttp://hdl.handle.net/10072/3830
dc.description.abstractThe ruthenium(II) complex, [RuCl2(NO)L] (I), (L=[(2-py)2PC2H4PO2(2-py)]-) was obtained from recrystallization of RuCl3NO(d2pype) (d2pype=(2-py)2PC2H4P(2-py)2) in the presence of HNO3, crystallizing in the monoclinic space group P21 (no. 4), with a =8.012(4) Ŭ b=14.454(4) Ŭ c=9.353(3) Ŭ ߽105.77(3)ଠand Z=2. Crystals of the DMSO solvate of the complex (II) were obtained from (CD3)2SO solution, crystallizing in the monoclinic space group P21/c (no.14) with a =9.7080(2) Ŭ b=22.2920(5) Ŭ c=11.5230(3) Ŭ ߽92.0450(10)ଠand Z=4. In both complexes, the geometry about the ruthenium atom is a distorted octahedron mainly as a result of the tridentate [P,N,O]-bonding mode of L. The ? (NO) bands at 1875 cm-1 in both complexes are consistent with the linear disposition of the NO group and the Ru atom as is observed in the X-ray crystal structure (Ru-N1-O1 angle=178.5(4)੮en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_US
dc.languageEnglishen_US
dc.language.isoen_US
dc.publisherNRC Research Pressen_US
dc.publisher.placeCanadaen_US
dc.relation.ispartofpagefrom1030en_US
dc.relation.ispartofpageto1035en_US
dc.relation.ispartofissue6en_US
dc.relation.ispartofjournalCanadian Journal of Chemistryen_US
dc.relation.ispartofvolume79en_US
dc.subject.fieldofresearchcode250299en_US
dc.titleA novel coordination mode for a pyridylphosphine ligand. X-ray structures of RuCl2(NO)(2-py)2PC2H4P=O,O-(2-py) (I) and RuCl2(NO)(2-py)2PC2H4P=O,O-(2-py).DMSO (II)en_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.date.issued2015-05-12T02:01:45Z
gro.hasfulltextNo Full Text


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