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dc.contributor.authorWang, Ruonan
dc.contributor.authorChen, Sibo
dc.contributor.authorNg, Yun Hau
dc.contributor.authorGao, Qiongzhi
dc.contributor.authorYang, Siyuan
dc.contributor.authorZhang, Shanqing
dc.contributor.authorPeng, Feng
dc.contributor.authorFang, Yueping
dc.contributor.authorZhang, Shengsen
dc.date.accessioned2019-07-04T12:36:18Z
dc.date.available2019-07-04T12:36:18Z
dc.date.issued2019
dc.identifier.issn1385-8947
dc.identifier.doi10.1016/j.cej.2019.01.073
dc.identifier.urihttp://hdl.handle.net/10072/383572
dc.description.abstractHigh performance, low cost and sustainable photocatalytic evolution of hydrogen is a promising energy supply alternative for modern society to resolve the depletion crisis of fossil fuel. The design of multi-heterojunction visible-light photocatalysts combined with electrochemical means is considered one of the most attractive options in recent years. In this work, a photoanode composed of top-opened ZnO/CdS/PbS nanotube arrays (ZnO/CdS/PbS ONTs) with multi-heterojunctions was synthesized via a three-step process, i.e. hydrothermal treatment, chemical bath deposition and successive ionic layer adsorption reaction (SILAR). This as-prepared photoanode exhibited remarkable photoelectrochemical activity under visible light irradiation. The photocurrent density and photoelectrochemical hydrogen evolution efficiency of the optimized ZnO/CdS/PbS ONTs reached up to 14.2 mA cm −2 and 5.5 mL cm −2 h −1 at 0.0 V vs. Ag/AgCl, respectively. The efficiency was 3.1 times that of top-closed ZnO/CdS nanotubes (1.8 mL cm −2 h −1 ). The experimental results suggest that the high photoelectrochemical activity can be ascribed to the inherent advantages of the structural and successive energy level relays design: on the one hand, the top-opened nanotube structure significantly enlarges surface area of the nanostructure, which facilitates efficient light absorption and rapid mass transport; on the other hand, the well-matched band energy edge of the multi-heterojunction interfaces literally build efficient electron highways to deliver electrons to reaction sites and reduce the recombination of photogenerated charge carriers.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.relation.ispartofpagefrom658
dc.relation.ispartofpageto666
dc.relation.ispartofjournalChemical Engineering Journal
dc.subject.fieldofresearchChemical Engineering
dc.subject.fieldofresearchCivil Engineering
dc.subject.fieldofresearchEnvironmental Engineering
dc.subject.fieldofresearchcode0904
dc.subject.fieldofresearchcode0905
dc.subject.fieldofresearchcode0907
dc.titleZnO/CdS/PbS nanotube arrays with multi-heterojunctions for efficient visible-light-driven photoelectrochemical hydrogen evolution
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhang, Shanqing


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