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dc.contributor.authorLoewe, Robert
dc.contributor.authorHanemann, Thomas
dc.contributor.authorHofmann, Andreas
dc.date.accessioned2019-07-04T12:33:17Z
dc.date.available2019-07-04T12:33:17Z
dc.date.issued2019
dc.identifier.issn1420-3049
dc.identifier.doi10.3390/molecules24020324
dc.identifier.urihttp://hdl.handle.net/10072/385181
dc.description.abstractEight new polymerizable ammonium-TFSI ionic liquids were synthesized and characterized with respect to an application in energy storage devices. The ionic liquids feature methacrylate or acrylate termination as polymerizable groups. The preparation was optimized to obtain the precursors and ionic liquids in high yield. All products were characterized by NMR and IR spectroscopy. Phase transition temperatures were obtained by DSC analysis. Density, viscosity and ionic conductivity of the ionic liquids were compared and discussed. The results reveal that the length of attached alkyl groups as well as the methyl group at the polymerizable function have significant influences on the ionic liquids physicochemical properties. Ionic conductivity values vary between 0.264 mS cm−1 for [C2NA,22]TFSI and 0.080 mS cm−1 for [C8NMA,22]TFSI at 25 °C. Viscosity values are within a range of 0.762 Pa s for [C2NA,22]TFSI and 1.522 Pa s for [C6NMA,22]TFSI at 25 °C.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherMDPI
dc.relation.ispartofissue2
dc.relation.ispartofjournalMOLECULES
dc.relation.ispartofvolume24
dc.subject.fieldofresearchMedicinal and biomolecular chemistry
dc.subject.fieldofresearchOrganic chemistry
dc.subject.fieldofresearchTheoretical and computational chemistry
dc.subject.fieldofresearchcode3404
dc.subject.fieldofresearchcode3405
dc.subject.fieldofresearchcode3407
dc.titlePolymerizable Ionic Liquids for Solid-State Polymer Electrolytes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextFull Text
gro.griffith.authorHofmann, Andreas


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