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dc.contributor.authorLiu, G
dc.contributor.authorCui, Z
dc.contributor.authorHan, M
dc.contributor.authorZhang, S
dc.contributor.authorZhao, C
dc.contributor.authorChen, C
dc.contributor.authorWang, G
dc.contributor.authorZhang, H
dc.date.accessioned2019-06-19T13:10:05Z
dc.date.available2019-06-19T13:10:05Z
dc.date.issued2019
dc.identifier.issn0947-6539
dc.identifier.doi10.1002/chem.201806377
dc.identifier.urihttp://hdl.handle.net/10072/385495
dc.description.abstractElectrosynthesis of NH3 through the N2 reduction reaction (NRR) under ambient conditions is regarded as promising technology to replace the industrial energy‐ and capital‐intensive Haber–Bosch process. Herein, a room‐temperature spontaneous redox approach to fabricate a core–shell‐structured Au@CeO2 composite, with Au nanoparticle sizes below about 10 nm and a loading amount of 3.6 wt %, is reported for the NRR. The results demonstrate that as‐synthesized Au@CeO2 possesses a surface area of 40.7 m2 g−1 and a porous structure. As an electrocatalyst, it exhibits high NRR activity, with an NH3 yield rate of 28.2 μg h−1 cm−2 (10.6 μg h−1 mg−1cat., 293.8 μg h−1 mg−1Au) and a faradaic efficiency of 9.50 % at −0.4 V versus a reversible hydrogen electrode in 0.01 m H2SO4 electrolyte. The characterization results reveal the presence of rich oxygen vacancies in the CeO2 nanoparticle shell of Au@CeO2; these are favorable for N2 adsorption and activation for the NRR. This has been further verified by theoretical calculations. The abundant oxygen vacancies in the CeO2 nanoparticle shell, combined with the Au nanoparticle core of Au@CeO2, are electrocatalytically active sites for the NRR, and thus, synergistically enhance the conversion of N2 into NH3.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofpagefrom5904
dc.relation.ispartofpageto5911
dc.relation.ispartofissue23
dc.relation.ispartofjournalChemistry - A European Journal
dc.relation.ispartofvolume25
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.titleAmbient Electrosynthesis of Ammonia on a Core–Shell‐Structured Au@CeO2 Catalyst: Contribution of Oxygen Vacancies in CeO2
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhang, Haimin


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