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dc.contributor.authorYuan, Q
dc.contributor.authorGong, W
dc.contributor.authorYe, Y
dc.contributor.authorLiu, J
dc.contributor.authorLin, Y
dc.contributor.authorChen, C
dc.contributor.authorZhang, H
dc.contributor.authorLi, P
dc.contributor.authorCheng, W
dc.contributor.authorWei, X
dc.contributor.authorLiang, C
dc.date.accessioned2019-06-25T02:06:43Z
dc.date.available2019-06-25T02:06:43Z
dc.date.issued2019
dc.identifier.issn1867-3880
dc.identifier.doi10.1002/cctc.201900517
dc.identifier.urihttp://hdl.handle.net/10072/385780
dc.description.abstractExploring novel catalyst supports with unique performance creates more opportunity for transforming organic chemicals in heterogeneous catalysis. In this paper, BiOCl is first presented as an effective support for Pd nanoparticles (NPs) toward application in the coupling reaction of benzaldehyde. The Cl− ion dissociates from BiOCl, which forms nucleophile with Pd nanoparticles; this is key for the one-step synthesis of benzoin ethyl ether, the conversion and selectivity of which can reach to 100 % and 97.9 % at 100 °C, respectively. DFT calculations reveal that Cl− ions can be stabilized by stronger Bi−Cl bonds through doping of Fe ions in substituting Bi sites in BiOCl. The parallel catalytic evaluation using Pd/Fe-doped BiOCl catalyst shows the suppression of coupling reaction, conversely, demonstrating the crucial role of nucleophile. This work provides new insights into support tailoring for the synthesis of vital organic chemicals in heterogeneous catalysis by changing chemical reaction pathway.
dc.description.peerreviewedYes
dc.publisherWILEY
dc.relation.ispartofpagefrom2676
dc.relation.ispartofpageto2682
dc.relation.ispartofissue11
dc.relation.ispartofjournalChemCatChem
dc.relation.ispartofvolume11
dc.subject.fieldofresearchInorganic chemistry
dc.subject.fieldofresearchPhysical chemistry
dc.subject.fieldofresearchChemical engineering
dc.subject.fieldofresearchcode3402
dc.subject.fieldofresearchcode3406
dc.subject.fieldofresearchcode4004
dc.titleConstruction of Pd/BiOCl Catalyst for Highly-selective Synthesis of Benzoin Ethyl Ether by Chlorine Promoted Coupling Reaction
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorZhang, Haimin


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