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dc.contributor.authorWang, Lin
dc.contributor.authorCao, Junhui
dc.contributor.authorCheng, Xiaodi
dc.contributor.authorLei, Chaojun
dc.contributor.authorDai, Qizhou
dc.contributor.authorYang, Bin
dc.contributor.authorLi, Zhongjian
dc.contributor.authorYounis, M Adnan
dc.contributor.authorLei, Lecheng
dc.contributor.authorHou, Yang
dc.contributor.authorOstrikov, Kostya
dc.date.accessioned2019-09-10T02:31:38Z
dc.date.available2019-09-10T02:31:38Z
dc.date.issued2019
dc.identifier.issn2168-0485en_US
dc.identifier.doi10.1021/acssuschemeng.9b01315en_US
dc.identifier.urihttp://hdl.handle.net/10072/387155
dc.description.abstractDevelopment of nonprecious metal-based electrocatalysts supporting hydrogen evolution reaction (HER) in the entire pH range has gained significant importance for harvesting green and renewable energy. Herein, we developed a novel electrocatalyst based on 3D carbon nanoarchitecture hybrid, which consists of CoP nanoparticles (CoP NPs) embedded into N-doped carbon nanotubes (NCNT), grafted on carbon polyhedron (CoP/NCNT-CP) that was prepared by carbonization and low-temperature phosphatization treatment of cobalt-based zeolite imidazole framework (ZIF). Benefiting from the strong synergistic effect and unique 3D structure, the CoP/NCNT-CP hybrid loaded on Ni foam exhibited excellent electrocatalytic HER performance in base with a low overpotential of 165 mV at a current density of 10 mA cm–2, which is competitive with the previously reported Co-based hybrid electrocatalysts. Furthermore, the CoP/NCNT-CP also demonstrated high HER electrocatalytic activities in both neutral and acidic conditions with the overpotentials of 203 and 305 mV at the current density of 10 mA cm–2. Additionally, the bifunctional CoP/NCNT-CP electrode simultaneously acted as an anode for hydrazine oxidation reaction (HzOR) and a cathode for HER. Excellent catalytic performance was demonstrated in base conditions with a low cell potential of 0.89 V at 10 mA cm–2, which was much lower than the voltage of overall water splitting (1.91 V) at the same current density.en_US
dc.description.peerreviewedYesen_US
dc.languageEnglishen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.ispartofpagefrom10044en_US
dc.relation.ispartofpageto10051en_US
dc.relation.ispartofissue11en_US
dc.relation.ispartofjournalACS Sustainable Chemistry and Engineeringen_US
dc.relation.ispartofvolume7en_US
dc.subject.fieldofresearchAnalytical Chemistryen_US
dc.subject.fieldofresearchOther Chemical Sciencesen_US
dc.subject.fieldofresearchcode0301en_US
dc.subject.fieldofresearchcode0399en_US
dc.subject.keywordsScience & Technologyen_US
dc.subject.keywordsPhysical Sciencesen_US
dc.subject.keywordsTechnologyen_US
dc.subject.keywordsChemistry, Multidisciplinaryen_US
dc.subject.keywordsGreen & Sustainable Science & Technologyen_US
dc.titleZIF-Derived Carbon Nanoarchitecture as a Bifunctional pH-Universal Electrocatalyst for Energy-Efficient Hydrogen Evolutionen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Articlesen_US
dcterms.bibliographicCitationWang, L; Cao, J; Cheng, X; Lei, C; Dai, Q; Yang, B; Li, Z; Younis, MA; Lei, L; Hou, Y; Ostrikov, K, ZIF-Derived Carbon Nanoarchitecture as a Bifunctional pH-Universal Electrocatalyst for Energy-Efficient Hydrogen Evolution, ACS Sustainable Chemistry and Engineering, 2019, 7 (11), pp. 10044-10051en_US
dc.date.updated2019-09-10T02:30:01Z
gro.hasfulltextNo Full Text
gro.griffith.authorOstrikov, Kostya (Ken)


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