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dc.contributor.authorLiu, Z
dc.contributor.authorGuan, D
dc.contributor.authorYu, Q
dc.contributor.authorXu, L
dc.contributor.authorZhuang, Z
dc.contributor.authorZhu, T
dc.contributor.authorZhao, D
dc.contributor.authorZhou, L
dc.contributor.authorMai, L
dc.date.accessioned2019-09-16T04:14:20Z
dc.date.available2019-09-16T04:14:20Z
dc.date.issued2018
dc.identifier.issn2405-8297en_US
dc.identifier.doi10.1016/j.ensm.2018.01.004en_US
dc.identifier.urihttp://hdl.handle.net/10072/387338
dc.description.abstractMonodisperse SiOx/C microspheres with tunable size (300–1000 nm) and well-controlled carbon content (~ 20–60 wt%) have been fabricated through a facile sol-gel method. The judicious selection of silicon and carbon precursors (vinyltriethoxysilane and resorcinol/formaldehyde) enables the formation of an homogeneous SiOx/C (x = 1.63) composite, in which the SiOx mainly exists as ultrafine nano-domains (<2 nm). Benefiting from the unique structural features, the resultant SiOx/C microspheres demonstrate high capacity and outstanding cyclability. Specifically, a reversible capacity of 999 mA h g−1 can be achieved at 100 mA g−1, retaining 853 mA h g−1 after 150 cycles. At 500 mA g−1, the SiOx/C delivers a specific capacity of 689 mA h g−1 and maintains 91.0% of the capacity after 400 cycles. SiOx/C//LiFePO4 full cells are also assembled, leading to an energy density of ~ 372 W h kg−1 based on the total mass of active materials. This work sheds light on the rational design of high-performance SiOx based anode materials for lithium-ion batteries.en_US
dc.description.peerreviewedYesen_US
dc.languageenen_US
dc.publisherElsevier BVen_US
dc.relation.ispartofpagefrom112en_US
dc.relation.ispartofpageto118en_US
dc.relation.ispartofjournalEnergy Storage Materialsen_US
dc.relation.ispartofvolume13en_US
dc.titleMonodisperse and homogeneous SiOx/C microspheres: A promising high-capacity and durable anode material for lithium-ion batteriesen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Articlesen_US
dcterms.bibliographicCitationLiu, Z; Guan, D; Yu, Q; Xu, L; Zhuang, Z; Zhu, T; Zhao, D; Zhou, L; Mai, L, Monodisperse and homogeneous SiOx/C microspheres: A promising high-capacity and durable anode material for lithium-ion batteries, Energy Storage Materials, 2018, 13, pp. 112-118en_US
dc.date.updated2019-09-16T04:13:15Z
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Dongyuan


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