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dc.contributor.authorZhu, H
dc.contributor.authorJing, Y
dc.contributor.authorPal, M
dc.contributor.authorLiu, Y
dc.contributor.authorLiu, Y
dc.contributor.authorWang, J
dc.contributor.authorZhang, F
dc.contributor.authorZhao, D
dc.date.accessioned2019-09-16T06:38:39Z
dc.date.available2019-09-16T06:38:39Z
dc.date.issued2017
dc.identifier.issn2040-3364en_US
dc.identifier.doi10.1039/c6nr08885fen_US
dc.identifier.urihttp://hdl.handle.net/10072/387366
dc.description.abstractHere, we report mesoporous TiO2@N-doped carbon composite nanospheres synthesized via a double-surfactant-assisted assembly sol-gel process followed by sequential carbonization of surfactants under a N2 atmosphere. The resulting TiO2@N-doped C composite nanospheres are composed of uniformly distributed TiO2 nanocrystals with a diameter of ∼8 nm coated by a N-doped carbon layer that was formed by surfactants. Moreover, a large number of connected mesopores were observed in the nanospheres after high-temperature carbonization treatment. The synthesized nanospheres possess a large specific surface area (∼120 m2 g-1) and a large pore size (4-40 nm), with a well-defined spherical structure and a diameter in the nanoscale range. As an anode material for lithium-ion batteries (LIB), the mesoporous composite nanospheres delivered a reversible capacity of ∼117 mA h g-1 after 2000 cycles at a current rate as high as 10 C, as well as superior rate capability. The N-doped carbon layers greatly improved the overall electrical conductivity of the mesoporous TiO2 nanospheres. This study provides a remarkable synthetic route for the preparation of mesoporous TiO2-based N-doped carbon composite materials as high-performance anode materials in LIBs.en_US
dc.description.peerreviewedYesen_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry (RSC)en_US
dc.relation.ispartofpagefrom1539en_US
dc.relation.ispartofpageto1546en_US
dc.relation.ispartofissue4en_US
dc.relation.ispartofjournalNanoscaleen_US
dc.relation.ispartofvolume9en_US
dc.subject.fieldofresearchTechnologyen_US
dc.subject.fieldofresearchPhysical Sciencesen_US
dc.subject.fieldofresearchChemical Sciencesen_US
dc.subject.fieldofresearchcode10en_US
dc.subject.fieldofresearchcode02en_US
dc.subject.fieldofresearchcode03en_US
dc.titleMesoporous TiO2@N-doped carbon composite nanospheres synthesized by the direct carbonization of surfactants after sol–gel process for superior lithium storageen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Articlesen_US
dcterms.bibliographicCitationZhu, H; Jing, Y; Pal, M; Liu, Y; Liu, Y; Wang, J; Zhang, F; Zhao, D, Mesoporous TiO2@N-doped carbon composite nanospheres synthesized by the direct carbonization of surfactants after sol–gel process for superior lithium storage, Nanoscale, 2017, 9 (4), pp. 1539-1546en_US
dc.date.updated2019-09-16T06:37:28Z
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Dongyuan


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