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dc.contributor.authorHan, Jianyu
dc.contributor.authorAn, Pengfei
dc.contributor.authorLiu, Shuhu
dc.contributor.authorZhang, Xiaofei
dc.contributor.authorWang, Dawei
dc.contributor.authorYuan, Yi
dc.contributor.authorGuo, Jun
dc.contributor.authorQiu, Xueying
dc.contributor.authorHou, Ke
dc.contributor.authorShi, Lin
dc.contributor.authorZhang, Yin
dc.contributor.authorZhao, Shenlong
dc.contributor.authorLong, Chang
dc.contributor.authorTang, Zhiyong
dc.date.accessioned2019-10-08T00:07:04Z
dc.date.available2019-10-08T00:07:04Z
dc.date.issued2019
dc.identifier.issn1433-7851
dc.identifier.doi10.1002/anie.201907399
dc.identifier.urihttp://hdl.handle.net/10072/388113
dc.description.abstractThe single‐site catalyst (SSC) characteristic of atomically dispersed active centers will not only maximize the catalytic activity, but also provide a promising platform for establishing the structure–activity relationship. However, arbitrary arrangements of active sites in the existed SSCs make it difficult for mechanism understanding and performance optimization. Now, a well‐defined ultrathin SSC is fabricated by assembly of metal‐porphyrin molecules, which enables the precise identification of the active sites for d‐orbital energy engineering. The activity of as‐assembled products for electrocatalytic CO2 reduction is significantly promoted via lifting up the energy level of metal durn:x-wiley:14337851:media:anie201907399:anie201907399-math-0001 orbitals, exhibiting a remarkable Faradaic efficiency of 96 % at the overpotential of 500 mV. Furthermore, a turnover frequency of 4.21 s−1 is achieved with negligible decay over 48 h.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofpagefrom12711
dc.relation.ispartofpageto12716
dc.relation.ispartofissue36
dc.relation.ispartofjournalAngewandte Chemie - International Edition
dc.relation.ispartofvolume58
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.subject.keywords2D materials
dc.subject.keywordsCO2 reduction
dc.subject.keywordselectrocatalysis
dc.subject.keywordsorbital reordering
dc.subject.keywordssingle-site catalysts
dc.titleReordering d Orbital Energies of Single‐Site Catalysts for CO2 Electroreduction
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationHan, J; An, P; Liu, S; Zhang, X; Wang, D; Yuan, Y; Guo, J; Qiu, X; Hou, K; Shi, L; Zhang, Y; Zhao, S; Long, C; Tang, Z, Reordering d Orbital Energies of Single-Site Catalysts for CO<inf>2</inf> Electroreduction, Angewandte Chemie - International Edition, 2019, 58 (36), pp. 12711-12716
dc.date.updated2019-10-08T00:03:33Z
gro.hasfulltextNo Full Text
gro.griffith.authorTang, Zhiyong


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