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dc.contributor.authorBatmunkh, Munkhbayar
dc.contributor.authorVimalanathan, Kasturi
dc.contributor.authorWu, Congcong
dc.contributor.authorBati, Abdulaziz SR
dc.contributor.authorYu, LePing
dc.contributor.authorTawfik, Sherif Abdulkader
dc.contributor.authorFord, Michael J
dc.contributor.authorMacdonald, Thomas J
dc.contributor.authorRaston, Colin L
dc.contributor.authorPriya, Shashank
dc.contributor.authorGibson, Christopher T
dc.contributor.authorShapter, Joseph G
dc.date.accessioned2019-10-09T06:01:38Z
dc.date.available2019-10-09T06:01:38Z
dc.date.issued2019
dc.identifier.issn2366-9608
dc.identifier.doi10.1002/smtd.201800521
dc.identifier.urihttp://hdl.handle.net/10072/388192
dc.description.abstractA simple and fast “top‐down” protocol is introduced herein to prepare solution processable few‐layer phosphorene nanosheets using vortex fluidic mediated exfoliation under near‐infrared (NIR) pulsed laser irradiation. This novel shear‐exfoliation method requires short processing times and produces highly crystalline, atomically thin phosphorene nanosheets (4.3 ± 0.4 nm). The as‐prepared phosphorene nanosheets are used as an effective electron transporting material (ETM) for low‐temperature processed, planar n‐i‐p perovskite solar cells (PSCs). With the addition of phosphorene, the average power conversion efficiency (PCE) increases from 14.32% to 16.53% with a maximum PCE of 17.85% observed for the phosphorene incorporated PSCs which is comparable to the devices made using the traditional high‐temperature protocol. Experimental and theoretical (density‐functional theory) investigations reveal the PCE improvements are due to the high carrier mobility and suitable band energy alignment of the phosphorene. The work not only paves the way for novel synthesis of 2D materials, but also opens a new avenue in using phosphorene as an efficient ETM in photovoltaic devices.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherWiley Blackwell
dc.relation.ispartofpagefrom1800521:1
dc.relation.ispartofpageto1800521:8
dc.relation.ispartofissue5
dc.relation.ispartofjournalSmall Methods
dc.relation.ispartofvolume3
dc.subject.fieldofresearchNanotechnology
dc.subject.fieldofresearchcode1007
dc.subject.keywordsScience & Technology
dc.subject.keywordsPhysical Sciences
dc.subject.keywordsChemistry, Physical
dc.subject.keywordsNanoscience & Nanotechnology
dc.titleEfficient Production of Phosphorene Nanosheets via Shear Stress Mediated Exfoliation for Low-Temperature Perovskite Solar Cells
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationBatmunkh, M; Vimalanathan, K; Wu, C; Bati, ASR; Yu, L; Tawfik, SA; Ford, MJ; Macdonald, TJ; Raston, CL; Priya, S; Gibson, CT; Shapter, JG, Efficient Production of Phosphorene Nanosheets via Shear Stress Mediated Exfoliation for Low-Temperature Perovskite Solar Cells, Small Methods, 2019, 3 (5), 1800521:1-1800521:8
dc.date.updated2019-10-09T06:00:15Z
gro.hasfulltextNo Full Text
gro.griffith.authorBatmunkh, Munkhbayar


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