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dc.contributor.authorZhang, Yin
dc.contributor.authorGuo, Jun
dc.contributor.authorShi, Lin
dc.contributor.authorZhu, Yanfei
dc.contributor.authorHou, Ke
dc.contributor.authorZheng, Yonglong
dc.contributor.authorTang, Zhiyong
dc.date.accessioned2020-02-24T00:28:55Z
dc.date.available2020-02-24T00:28:55Z
dc.date.issued2017
dc.identifier.issn2375-2548
dc.identifier.doi10.1126/sciadv.1701162
dc.identifier.urihttp://hdl.handle.net/10072/391801
dc.description.abstractA simple and effective strategy is developed to realize visible light–driven heterogeneous asymmetric catalysis. A chiral organic molecule, which only has very weak catalytic activity in asymmetric α-alkylation of aldehydes under visible light, is utilized as the ligand to coordinate with different types of metal ions, including Zn2+, Zr4+, and Ti4+, for construction of crystalline metal organic frameworks (MOFs). Impressively, when used as heterogeneous catalysts, all of the synthesized MOFs exhibit markedly enhanced activity. Furthermore, the asymmetric catalytic performance of these MOFs could be easily altered by selecting different metal ions, owing to the tunable electron transfer property between metal ions and chiral ligands. This work will provide a new approach for fabrication of heterogeneous catalysts and trigger more enthusiasm to conduct the asymmetric catalysis driven by visible light.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Association for the Advancement of Science
dc.relation.ispartofissue8
dc.relation.ispartofjournalScience Advances
dc.relation.ispartofvolume3
dc.subject.keywordsScience & Technology
dc.subject.keywordsMultidisciplinary Sciences
dc.subject.keywordsScience & Technology - Other Topics
dc.subject.keywordsPHOTOREDOX ORGANOCATALYSIS
dc.subject.keywordsALPHA-ALKYLATION
dc.titleTunable chiral metal organic frameworks toward visible light-driven asymmetric catalysis
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationZhang, Y; Guo, J; Shi, L; Zhu, Y; Hou, K; Zheng, Y; Tang, Z, Tunable chiral metal organic frameworks toward visible light-driven asymmetric catalysis, Science Advances, 2017, 3 (8)
dcterms.dateAccepted2017-07-17
dcterms.licensehttps://creativecommons.org/licenses/by-nc/4.0/
dc.date.updated2020-02-24T00:26:33Z
dc.description.versionVersion of Record (VoR)
gro.rights.copyright© 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).
gro.hasfulltextFull Text
gro.griffith.authorTang, Zhiyong


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