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dc.contributor.authorQiu, Xueying
dc.contributor.authorZhu, Yanfei
dc.contributor.authorZhang, Xiaofei
dc.contributor.authorZhang, Yin
dc.contributor.authorMenisa, Leta Takele
dc.contributor.authorXia, Chonghan
dc.contributor.authorLiu, Shaoqin
dc.contributor.authorTang, Zhiyong
dc.date.accessioned2020-03-13T02:37:14Z
dc.date.available2020-03-13T02:37:14Z
dc.date.issued2019
dc.identifier.issn2367-198X
dc.identifier.doi10.1002/solr.201900449
dc.identifier.urihttp://hdl.handle.net/10072/392318
dc.description.abstractMetal–organic frameworks (MOFs), a new fascinating class of photocatalysts, have attracted considerable interest in the past few years. Unfortunately, the photocatalytic activities of most pristine MOFs are limited by their intrinsic drawbacks such as limited visible light absorption and poor charge separation efficiency. Herein, a series of Ce‐UiOs are constructed through metal substitution and ligand modification, and their photocatalytic properties are studied systematically. Due to the low‐lying empty 4f orbitals of Ce, the light absorption range of as‐prepared Ce‐UiO MOFs is extended to the visible light region. Moreover, their negative ligand‐to‐metal charge transfer energy (ELMCT) facilitates the separation of charge carriers, which leads to the efficient visible light oxidation of benzyl alcohol. The possible reaction mechanism is validated by electrochemical test and photoluminescence spectroscopy. This work provides an entire new set of Ce‐MOFs‐based photocatalysts for future important inorganic reactions.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofjournalSolar RRL
dc.subject.fieldofresearchNanotechnology
dc.subject.fieldofresearchcode1007
dc.subject.keywordsScience & Technology
dc.subject.keywordsTechnology
dc.subject.keywordsEnergy & Fuels
dc.subject.keywordsMaterials Science, Multidisciplinary
dc.subject.keywordsMaterials Science
dc.titleCerium-Based Metal-Organic Frameworks with UiO Architecture for Visible Light-Induced Aerobic Oxidation of Benzyl Alcohol
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationQiu, X; Zhu, Y; Zhang, X; Zhang, Y; Menisa, LT; Xia, C; Liu, S; Tang, Z, Cerium-Based Metal-Organic Frameworks with UiO Architecture for Visible Light-Induced Aerobic Oxidation of Benzyl Alcohol, Solar RRL, 2019
dc.date.updated2020-03-12T00:04:10Z
gro.description.notepublicThis publication has been entered into Griffith Research Online as an Advanced Online Version.
gro.hasfulltextNo Full Text
gro.griffith.authorTang, Zhiyong


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