Tuning the Properties of Metal–Organic Frameworks by Post‐synthetic Modification
Author(s)
Burrows, Andrew D
Cadman, Laura K
Gee, William
Hamzah, Harina Amer
Knichal, Jane V
Rochat, Sébastien
Griffith University Author(s)
Year published
2018
Metadata
Show full item recordAbstract
This chapter introduces the concept of post‐synthetic modification (PSM) in metal–organic framework (MOF) chemistry and provides examples of the use of this technique for a variety of applications. Following a brief introduction (Section 2.1), the different types of PSM reactions are described in Section 2.2. These include covalent transformations to the linker and modification of the inorganic part of the framework through exchange of ligands or metal centers. The next sections concentrate on the use of post‐synthetically modified MOFs for different applications, focusing on gas adsorption and separations (Section 2.3), ...
View more >This chapter introduces the concept of post‐synthetic modification (PSM) in metal–organic framework (MOF) chemistry and provides examples of the use of this technique for a variety of applications. Following a brief introduction (Section 2.1), the different types of PSM reactions are described in Section 2.2. These include covalent transformations to the linker and modification of the inorganic part of the framework through exchange of ligands or metal centers. The next sections concentrate on the use of post‐synthetically modified MOFs for different applications, focusing on gas adsorption and separations (Section 2.3), catalysis (Section 2.4), sequestration and solution phase separations (Section 2.5), and biomedical applications (Section 2.6). In each case the properties of post‐synthetically modified MOFs are compared with those of their non‐modified analogues. Section 2.7 describes systems in which properties are modified through cross‐linking of ligands, and finally, Section 2.8 provides some general conclusions.
View less >
View more >This chapter introduces the concept of post‐synthetic modification (PSM) in metal–organic framework (MOF) chemistry and provides examples of the use of this technique for a variety of applications. Following a brief introduction (Section 2.1), the different types of PSM reactions are described in Section 2.2. These include covalent transformations to the linker and modification of the inorganic part of the framework through exchange of ligands or metal centers. The next sections concentrate on the use of post‐synthetically modified MOFs for different applications, focusing on gas adsorption and separations (Section 2.3), catalysis (Section 2.4), sequestration and solution phase separations (Section 2.5), and biomedical applications (Section 2.6). In each case the properties of post‐synthetically modified MOFs are compared with those of their non‐modified analogues. Section 2.7 describes systems in which properties are modified through cross‐linking of ligands, and finally, Section 2.8 provides some general conclusions.
View less >
Book Title
Metal‐Organic Frameworks: Applications in Separations and Catalysis
Copyright Statement
Self-archiving is not yet supported by this publisher. Please refer to the publisher's website or contact the author(s) for more information.
Subject
Metal organic frameworks
Inorganic materials (incl. nanomaterials)
Macromolecular materials
Nanochemistry