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dc.contributor.authorWang, Weikang
dc.contributor.authorZhou, Hongjian
dc.contributor.authorLiu, Yanyan
dc.contributor.authorZhang, Shengbo
dc.contributor.authorZhang, Yunxia
dc.contributor.authorWang, Guozhong
dc.contributor.authorZhang, Haimin
dc.contributor.authorZhao, Huijun
dc.date.accessioned2020-07-10T02:54:33Z
dc.date.available2020-07-10T02:54:33Z
dc.date.issued2020
dc.identifier.issn1613-6810
dc.identifier.doi10.1002/smll.201906880
dc.identifier.urihttp://hdl.handle.net/10072/395318
dc.description.abstractIt is an important issue that exposed active nitrogen atoms (e.g., edge or amino N atoms) in graphitic carbon nitride (g‐C3N4) could participate in ammonia (NH3) synthesis during the photocatalytic nitrogen reduction reaction (NRR). Herein, the experimental results in this work demonstrate that the exposed active N atoms in g‐C3N4 nanosheets can indeed be hydrogenated and contribute to NH3 synthesis during the visible‐light photocatalytic NRR. However, these exposed N atoms can be firmly stabilized through forming B-N-C coordination by means of B‐doping in g‐C3N4 nanosheets (BCN) with a B‐doping content of 13.8 wt%. Moreover, the formed BNC coordination in g‐C3N4 not only effectively enhances the visible‐light harvesting and suppresses the recombination of photogenerated carriers in g‐C3N4, but also acts as the catalytic active site for N2 adsorption, activation, and hydrogenation. Consequently, the as‐synthesized BCN exhibits high visible‐light‐driven photocatalytic NRR activity, affording an NH3 yield rate of 313.9 µmol g−1 h−1, nearly 10 times of that for pristine g‐C3N4. This work would be helpful for designing and developing high‐efficiency metal‐free NRR catalysts for visible‐light‐driven photocatalytic NH3 synthesis.
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherWiley
dc.relation.ispartofpagefrom1906880:1
dc.relation.ispartofpageto1906880:9
dc.relation.ispartofissue13
dc.relation.ispartofjournalSmall
dc.relation.ispartofvolume16
dc.subject.fieldofresearchNanotechnology
dc.subject.fieldofresearchcode1007
dc.subject.keywordsScience & Technology
dc.subject.keywordsPhysical Sciences
dc.subject.keywordsChemistry, Multidisciplinary
dc.subject.keywordsChemistry, Physical
dc.titleFormation of B-N-C Coordination to Stabilize the Exposed Active Nitrogen Atoms in g-C3N4 for Dramatically Enhanced Photocatalytic Ammonia Synthesis Performance
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationWang, W; Zhou, H; Liu, Y; Zhang, S; Zhang, Y; Wang, G; Zhang, H; Zhao, H, Formation of B-N-C Coordination to Stabilize the Exposed Active Nitrogen Atoms in g-C3N4 for Dramatically Enhanced Photocatalytic Ammonia Synthesis Performance, Small, 2020, 16 (13), pp. 1906880:1-1906880:9
dc.date.updated2020-07-10T02:48:35Z
gro.hasfulltextNo Full Text
gro.griffith.authorZhang, Haimin
gro.griffith.authorZhao, Huijun


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