Plasma-induced on-surface sulfur vacancies in NiCo2S4 enhance the energy storage performance of supercapatteries
Author(s)
Wang, Xiaoxiang
Zhou, Rusen
Zhang, Chunmei
Xi, Shibo
Jones, Michael WM
Tesfamichael, Tuquabo
Du, Aijun
Gui, Ke
Ostrikov, Kostya Ken
Wang, Hongxia
Griffith University Author(s)
Year published
2020
Metadata
Show full item recordAbstract
Vacancies have received considerable attention in energy storage materials since they are able to generate more active defects, leading to enhanced conductivity and thus higher capability. Here, we provide a facile strategy to rapidly achieve sufficient sulphur vacancies, lattice distortion and changed charge-states of Ni/Co on the material surface layer in NiCo2S4via low-temperature atmospheric pressure plasma. Both experimental results and DFT calculations have demonstrated that enhanced performances can be obtained with different amounts of sulphur vacancies (S-vacancies), with optimal performance obtained at 30% S-vacancy. ...
View more >Vacancies have received considerable attention in energy storage materials since they are able to generate more active defects, leading to enhanced conductivity and thus higher capability. Here, we provide a facile strategy to rapidly achieve sufficient sulphur vacancies, lattice distortion and changed charge-states of Ni/Co on the material surface layer in NiCo2S4via low-temperature atmospheric pressure plasma. Both experimental results and DFT calculations have demonstrated that enhanced performances can be obtained with different amounts of sulphur vacancies (S-vacancies), with optimal performance obtained at 30% S-vacancy. Moreover, the same trend of enhanced energy storage performance effects is found in comparison groups of varied Ni/Co atomic ratios (1 : 1, 2 : 1, 1 : 4, 4 : 1), suggesting the serviceability of this facile strategy, which only requires 30 seconds of processing. This paves a path towards high-performance supercapatteries using the simple plasma-based method.
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View more >Vacancies have received considerable attention in energy storage materials since they are able to generate more active defects, leading to enhanced conductivity and thus higher capability. Here, we provide a facile strategy to rapidly achieve sufficient sulphur vacancies, lattice distortion and changed charge-states of Ni/Co on the material surface layer in NiCo2S4via low-temperature atmospheric pressure plasma. Both experimental results and DFT calculations have demonstrated that enhanced performances can be obtained with different amounts of sulphur vacancies (S-vacancies), with optimal performance obtained at 30% S-vacancy. Moreover, the same trend of enhanced energy storage performance effects is found in comparison groups of varied Ni/Co atomic ratios (1 : 1, 2 : 1, 1 : 4, 4 : 1), suggesting the serviceability of this facile strategy, which only requires 30 seconds of processing. This paves a path towards high-performance supercapatteries using the simple plasma-based method.
View less >
Journal Title
Journal of Materials Chemistry A
Volume
8
Issue
18
Subject
Macromolecular and materials chemistry
Materials engineering
Other engineering
Science & Technology
Physical Sciences
Chemistry, Physical
Energy & Fuels