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dc.contributor.authorLv, Yang
dc.contributor.authorHan, Miaomiao
dc.contributor.authorGong, Wanbing
dc.contributor.authorWang, Dongdong
dc.contributor.authorChen, Chun
dc.contributor.authorWang, Guozhong
dc.contributor.authorZhang, Haimin
dc.contributor.authorZhao, Huijun
dc.date.accessioned2020-09-21T05:16:03Z
dc.date.available2020-09-21T05:16:03Z
dc.date.issued2020
dc.identifier.issn1521-3773
dc.identifier.doi10.1002/anie.202009913
dc.identifier.urihttp://hdl.handle.net/10072/397730
dc.description.abstractSelective hydrogenation of C=O against the conjugated C=C in cinnamaldehyde (CAL) is indispensable to produce cinnamyl alcohol (COL), nonetheless, challenged by the low selectivity and the need to use organic solvents. Herein, for the first time, we report the use of Fe-Co alloy nanoparticles (NPs) on N-doped carbon support as a selective hydrogenation catalyst to efficiently convert CAL to COL. The resultant catalyst with the optimized Fe/Co ratio of 0.5 can achieve an exceptional COL selectivity of 91.7% at a CAL conversion of 95.1% in pure water medium under mild reaction conditions, ranking it the best performed catalyst reported to date. The experimental results confirm that the COL selectivity and CAL conversion efficiency are respectively promoted by the presence of Co and Fe, while the synergism of the alloyed Fe-Co is the key to concurrently achieve high COL selectivity and CAL conversion efficiency .
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.relation.ispartofjournalAngewandte Chemie International Edition
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode03
dc.subject.keywordsCinnamaldehyde
dc.subject.keywordsFe-Co nanoalloys
dc.subject.keywordsH2O solvent
dc.subject.keywordsMetal-organic frameworks
dc.subject.keywordsselective hydrogenation
dc.titleFe-Co Alloyed Nanoparticles Catalysed Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationLv, Y; Han, M; Gong, W; Wang, D; Chen, C; Wang, G; Zhang, H; Zhao, H, Fe-Co Alloyed Nanoparticles Catalysed Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water, Angewandte Chemie International Edition, 2020
dcterms.dateAccepted2020-09-09
dc.date.updated2020-09-21T04:37:52Z
dc.description.versionAccepted Manuscript (AM)
gro.description.notepublicThis publication has been entered in Griffith Research Online as an advanced online version.
gro.rights.copyright© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Fe‐Co Alloyed Nanoparticles Catalysed Efficient Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol in Water, Angewandte Chemie, International Edition, 2020, which has been published in final form at https://doi.org/10.1002/anie.202009913. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving (http://olabout.wiley.com/WileyCDA/Section/id-828039.html)
gro.hasfulltextFull Text
gro.griffith.authorZhao, Huijun
gro.griffith.authorZhang, Haimin


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