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dc.contributor.authorSmith, Graham
dc.contributor.authorWermuth, Urs D
dc.date.accessioned2017-05-03T14:50:07Z
dc.date.available2017-05-03T14:50:07Z
dc.date.issued2011
dc.date.modified2012-04-29T22:25:46Z
dc.identifier.issn1600-5368
dc.identifier.doi10.1107/S1600536810052694
dc.identifier.urihttp://hdl.handle.net/10072/39783
dc.description.abstractIn polymeric title compound, {[Co2(C7H2N2O7)2(H2O)6]孍 2H2O}n, obtained from the reaction of 3,5-dinitrosalicylic acid with cobalt(II) acetate, both CoII atoms are located on inversion centres and exhibit a distorted octahedral coordination geometry. The coordination sphere about one CoII atom comprises four O-atom donors from two bidentate chelate (Ophenolate and Ocarboxyl) and bridging dianionic ligands and two water molecules [Co-O range = 2.0249 (11)- 2.1386 (14) A ࠝ, while that about the second CoII atom has four water molecules and two bridging carboxylate O-donor atoms [Co-O range = 2.0690 (14)-2.1364 (11) A ࠝ. The coordinated water molecules as well as the water molecules of solvation give O-H啕O water-water and water-carboxyl hydrogen-bonding interactions in the three-dimensional framework structure.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.format.extent715800 bytes
dc.format.mimetypeapplication/pdf
dc.languageEnglish
dc.language.isoen_US
dc.publisherWiley-Blackwell Publishing
dc.publisher.placeUnited States
dc.publisher.urihttp://journals.iucr.org/e/issues/2011/01/00/issconts.html
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefromm119
dc.relation.ispartofpagetom120
dc.relation.ispartofissue1
dc.relation.ispartofjournalActa Crystallographica. Section E: Structure Reports Online
dc.relation.ispartofvolumeE67
dc.rights.retentionY
dc.subject.fieldofresearchStructural Chemistry and Spectroscopy
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchcode030606
dc.subject.fieldofresearchcode03
dc.titlecatena-Poly[[[diaquacobalt(II)]-[mu]-(3,5-dinitro-2-oxidobenzoato)-[kappa]3O1,O2:O1'-[tetraaquacobalt(II)]-[mu]-(3,5-dinitro-2-oxidobenzoato)-[kappa]3O1:O1',O2] dihydrate]
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
dcterms.licensehttp://creativecommons.org/licenses/by/2.0/uk/legalcode
gro.rights.copyright© The Author(s) 2011. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
gro.date.issued2011
gro.hasfulltextFull Text
gro.griffith.authorWermuth, Urs D.


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