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dc.contributor.authorLiu, Hongweien_US
dc.contributor.authorR. Waclawik, Ericen_US
dc.contributor.authorZheng, Zhanfengen_US
dc.contributor.authorYang, Dongjiangen_US
dc.contributor.authorKe, Xuebinen_US
dc.contributor.authorZhu, Huaiyongen_US
dc.contributor.authorL. Frost, Rayen_US
dc.date.accessioned2017-04-24T12:19:29Z
dc.date.available2017-04-24T12:19:29Z
dc.date.issued2010en_US
dc.date.modified2011-08-12T06:19:52Z
dc.identifier.issn19327447en_US
dc.identifier.doi10.1021/jp103644xen_AU
dc.identifier.urihttp://hdl.handle.net/10072/39911
dc.description.abstractSodium and hydrogen titanates fibers and three TiO2 polymorphs (TiO2 (B), anatase, and rutile) were prepared from inorganic titanium compounds by hydrothermal reaction and calcination. The nature and morphologies of the nanofibers with layered structure were investigated by means of X-ray diffraction (XRD) and transmission electron microscopy (TEM). It was revealed that the phase transitions between titanates and titania (via proton titanate) could be interpreted systemically by the fundamental building blocks (FBB) model. The reaction also requires interconversion between some corner-linked and edge-linked pairs of TiO6 octahedrons. A generalized relationship of phase transitions between sodium/hydrogen titanates and titania by the wet-chemical process was proposed. A duplex pentagonal prism scheme was implied to summarize all of the phase relationships between titanates and titania.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_AU
dc.languageEnglishen_US
dc.language.isoen_AU
dc.publisherAmerican Chemical Societyen_US
dc.publisher.placeUnited Statesen_US
dc.relation.ispartofstudentpublicationNen_AU
dc.relation.ispartofpagefrom11430en_US
dc.relation.ispartofpageto11434en_US
dc.relation.ispartofissue26en_US
dc.relation.ispartofjournalThe Journal of Physical Chemistry Cen_US
dc.relation.ispartofvolume114en_US
dc.rights.retentionYen_AU
dc.subject.fieldofresearchMacromolecular and Materials Chemistry not elsewhere classifieden_US
dc.subject.fieldofresearchcode030399en_US
dc.titleTEM Investigation and FBB Model Explanation to the Phase Relationships between Titanates and Titanium Dioxidesen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.rights.copyrightSelf-archiving of the author-manuscript version is not yet supported by this journal. Please refer to the journal link for access to the definitive, published version or contact the author[s] for more information.en_AU
gro.date.issued2010
gro.hasfulltextNo Full Text


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