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  • Coordination complexes of silver(I) with tertiary phosphine and related ligands

    Author(s)
    Meijboom, Reinout
    Bowen, Richard J
    Berners-Price, Susan J
    Griffith University Author(s)
    Berners-Price, Sue J.
    Year published
    2009
    Metadata
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    Abstract
    This paper gives an overview of the structural chemistry of silver(I) coordination complexes. The main discussion is on the halide complexes (F-, Cl-, Br-, I-) but included are also the pseudo-halides (CN-, SCN-) and the classical non-coordinating anions (NO3-, ClO4-, BF4-, PF6-) and oxy-anions (NO3-, H3CCO2-, F3CCO2-, F3CSO3-, etc.). The main focus is on complexes of these silver(I) salts with phosphine ligands, but where relevant the chemistry of other donor ligands is also reviewed. Coordination complexes of silver(I) halides show a rich variation of structural types. The type of structure depends on the stoichiometry of ...
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    This paper gives an overview of the structural chemistry of silver(I) coordination complexes. The main discussion is on the halide complexes (F-, Cl-, Br-, I-) but included are also the pseudo-halides (CN-, SCN-) and the classical non-coordinating anions (NO3-, ClO4-, BF4-, PF6-) and oxy-anions (NO3-, H3CCO2-, F3CCO2-, F3CSO3-, etc.). The main focus is on complexes of these silver(I) salts with phosphine ligands, but where relevant the chemistry of other donor ligands is also reviewed. Coordination complexes of silver(I) halides show a rich variation of structural types. The type of structure depends on the stoichiometry of the ligand to silver in the reaction mixture, as well as reaction conditions. Other factors influencing the structure of these complexes include the halide or pseudo-halide ligands used as counterion and the type of solvent.
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    Journal Title
    Coordination Chemistry Reviews
    Volume
    253
    Issue
    3-4
    DOI
    https://doi.org/10.1016/j.ccr.2008.03.001
    Subject
    Classical physics not elsewhere classified
    Inorganic chemistry
    Physical chemistry
    Other chemical sciences
    Publication URI
    http://hdl.handle.net/10072/39941
    Collection
    • Journal articles

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