Interface modification using a post-treatment-free heteropolyacid for effective charge selective bilayer formation in perovskite solar cells
Author(s)
Saianand, Gopalan
Gopalan, Anantha-Iyengar
Roy, Vellaisamy AL
Wilson, Gregory J
Jakmunee, Jaroon
Sonar, Prashant
Lin, Liangyou
Kim, Sae-Wan
Kang, Shin-Won
Griffith University Author(s)
Year published
2020
Metadata
Show full item recordAbstract
We rationally utilized a solution-processed post-heat treatment-free heteropolyacid compound, phosphomolybdic acid hydrate (PMAH) as a charge selective interface modifier for poly(3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT:PSS) in inverted perovskite solar cells (PSCs). The fabricated PSCs with PMAH/PEDOT:PSS bilayer exhibited significant improvement in the power conversion efficiency (PCE) (∼12%) with superior long-term air-stability as compared to PEDOT:PSS based PSCs (9.8%). The measured photovoltaic performance demonstrates that the inclusion of PMAH as an interface to ITO and PEDOT:PSS is an efficient ...
View more >We rationally utilized a solution-processed post-heat treatment-free heteropolyacid compound, phosphomolybdic acid hydrate (PMAH) as a charge selective interface modifier for poly(3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT:PSS) in inverted perovskite solar cells (PSCs). The fabricated PSCs with PMAH/PEDOT:PSS bilayer exhibited significant improvement in the power conversion efficiency (PCE) (∼12%) with superior long-term air-stability as compared to PEDOT:PSS based PSCs (9.8%). The measured photovoltaic performance demonstrates that the inclusion of PMAH as an interface to ITO and PEDOT:PSS is an efficient way of realizing stable and efficient PSCs.
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View more >We rationally utilized a solution-processed post-heat treatment-free heteropolyacid compound, phosphomolybdic acid hydrate (PMAH) as a charge selective interface modifier for poly(3,4-ethylene dioxythiophene): polystyrene sulfonate (PEDOT:PSS) in inverted perovskite solar cells (PSCs). The fabricated PSCs with PMAH/PEDOT:PSS bilayer exhibited significant improvement in the power conversion efficiency (PCE) (∼12%) with superior long-term air-stability as compared to PEDOT:PSS based PSCs (9.8%). The measured photovoltaic performance demonstrates that the inclusion of PMAH as an interface to ITO and PEDOT:PSS is an efficient way of realizing stable and efficient PSCs.
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Journal Title
Materials Letters
Volume
277
Subject
Physical sciences
Chemical sciences
Engineering
Science & Technology
Materials Science, Multidisciplinary
Physics, Applied