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dc.contributor.authorZhou, Ming
dc.contributor.authorLi, Tianling
dc.contributor.authorXing, Chao
dc.contributor.authorLiu, Yang
dc.contributor.authorZhao, Huijun
dc.date.accessioned2020-12-17T04:48:22Z
dc.date.available2020-12-17T04:48:22Z
dc.date.issued2020
dc.identifier.issn0003-2700
dc.identifier.doi10.1021/acs.analchem.0c02997
dc.identifier.urihttp://hdl.handle.net/10072/400337
dc.description.abstractHighly toxic chlorine gas imposes serious health risks in the workplace. The ability to on-site, real-time monitoring of instantaneous and time-weighted average (TWA) chlorine gas concentrations in a simple, sensitive, accurate, and reliable manner would be highly beneficial to improve workplace health and safety. Here, we propose and experimentally validate a gaseous chlorine detection principle based on a N,N-diethyl-p-phenylenediamine sulfate salt/Cl2 colorimetric reaction-controlled membrane process to regulate the gaseous chlorine transport across a gas-permeable membrane that enables the establishment of a time-resolved analytical relationship to quantify chlorine concentration by multidata points with dramatically enhanced accuracy and reliability. A gas-permeable membrane-based portable colorimetric gaseous chlorine sensing probe (MCSP) was designed and fabricated. The MCSP embedded the proposed analytical principle that is capable of real-time continuous monitoring of the instantaneous and TWA chlorine gas concentrations within an analytical range of 0.009–2.058 mg L–1 without the need for on-going calibration, which could be a useful analytical tool for managing the toxic chlorine gas-imposed health risks in workplaces.
dc.description.peerreviewedYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society (ACS)
dc.relation.ispartofjournalAnalytical Chemistry
dc.subject.fieldofresearchAnalytical chemistry
dc.subject.fieldofresearchOther chemical sciences
dc.subject.fieldofresearchMedical biochemistry and metabolomics
dc.subject.fieldofresearchChemical engineering
dc.subject.fieldofresearchcode3401
dc.subject.fieldofresearchcode3499
dc.subject.fieldofresearchcode3205
dc.subject.fieldofresearchcode4004
dc.titleMembrane-Based Portable Colorimetric Gaseous Chlorine Sensing Probe
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationZhou, M; Li, T; Xing, C; Liu, Y; Zhao, H, Membrane-Based Portable Colorimetric Gaseous Chlorine Sensing Probe., Analytical Chemistry, 2020
dc.date.updated2020-12-17T03:48:08Z
gro.hasfulltextNo Full Text
gro.griffith.authorZhou, Ming
gro.griffith.authorZhao, Huijun


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