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dc.contributor.authorTian, Y
dc.contributor.authorLiu, X
dc.contributor.authorXu, L
dc.contributor.authorYuan, D
dc.contributor.authorDou, Y
dc.contributor.authorQiu, J
dc.contributor.authorLi, H
dc.contributor.authorMa, J
dc.contributor.authorWang, Y
dc.contributor.authorSu, D
dc.contributor.authorZhang, S
dc.date.accessioned2021-03-22T00:58:37Z
dc.date.available2021-03-22T00:58:37Z
dc.date.issued2021
dc.identifier.issn1616-301X
dc.identifier.doi10.1002/adfm.202101239
dc.identifier.urihttp://hdl.handle.net/10072/403339
dc.description.abstractEfficient oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) processes highly rely on the rational design and synthesis of high‐performance electrocatalysts. Herein, comprehensive characterizations and density functional theory (DFT) calculations are combined to verify the important roles of the crystallinity and oxygen vacancy levels of Co(II) oxide (CoO) on ORR and OER activities. A facile and controllable vacuum‐calcination strategy is utilized to convert Co(OH)2 into oxygen‐defective amorphous‐crystalline CoO (namely ODAC‐CoO) nanosheets. With the carefully controlled crystallinity and oxygen vacancy levels, the optimal ODAC‐CoO sample exhibits dramatically enhanced ORR and OER electrocatalytic activities compared with the pure crystalline CoO counterpart. The assembled liquid and quasi‐solid‐state Zn–air batteries with ODAC‐CoO as cathode material achieve remarkable specific capacity, power density, and excellent cycling stability, outperforming the benchmark Pt/C+IrO2 catalysts. This study theoretically proposes and experimentally demonstrates that the simultaneous introduction of amorphous structures and oxygen vacancies could be an effective avenue towards high‐performance electrocatalytic ORR and OER.
dc.description.peerreviewedYes
dc.languageen
dc.publisherWiley
dc.relation.ispartofjournalAdvanced Functional Materials
dc.subject.fieldofresearchPhysical Sciences
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchcode02
dc.subject.fieldofresearchcode03
dc.subject.fieldofresearchcode09
dc.titleEngineering Crystallinity and Oxygen Vacancies of Co(II) Oxide Nanosheets for High Performance and Robust Rechargeable Zn–Air Batteries
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationTian, Y; Liu, X; Xu, L; Yuan, D; Dou, Y; Qiu, J; Li, H; Ma, J; Wang, Y; Su, D; Zhang, S, Engineering Crystallinity and Oxygen Vacancies of Co(II) Oxide Nanosheets for High Performance and Robust Rechargeable Zn–Air Batteries, Advanced Functional Materials, 2021
dc.date.updated2021-03-22T00:06:32Z
gro.description.notepublicThis publication has been entered in Griffith Research Online as an advanced online version.
gro.hasfulltextNo Full Text
gro.griffith.authorTian, Yuhui
gro.griffith.authorDou, Yuhai
gro.griffith.authorWang, Yun
gro.griffith.authorZhang, Shanqing
gro.griffith.authorYuan, Ding


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