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dc.contributor.authorZhang, P
dc.contributor.authorTian, Z
dc.contributor.authorHung, CT
dc.contributor.authorLiu, Y
dc.contributor.authorJia, B
dc.contributor.authorLan, K
dc.contributor.authorKong, B
dc.contributor.authorHuang, F
dc.contributor.authorMai, L
dc.contributor.authorZhao, D
dc.date.accessioned2021-04-08T22:40:17Z
dc.date.available2021-04-08T22:40:17Z
dc.date.issued2020
dc.identifier.issn2666-3864
dc.identifier.doi10.1016/j.xcrp.2020.100081
dc.identifier.urihttp://hdl.handle.net/10072/403628
dc.description.abstractThe understanding and control of the structural complexity of mesoporous semiconductors with single-crystal-like nature are both attractive and challenging. Here, we report a crystallization-driven epitaxial assembly from monomicelles to construct branched mesoporous TiO mesocrystals (m-TiO MCs) with coherent atomic domains. The star-shaped multipods are obtained by two-step evaporation with nanocrystal mediation, primarily consisting of arms along < 001 >, < 101 >, and < 111 > crystal directions. For each arm, ordered open mesochannels arrange in parallel along the growth direction. The m-TiO MC multipods have a surface area of ∼116 m /g and single-crystal-like frameworks and are good hydrogen evolution photocatalysts. Under full-spectrum irradiation, the branched m-TiO MCs exhibit a hydrogen evolution rate of 8 mmol h g , which is more than four times higher than that of commercial TiO P25. This crystallization-driven self-assembly approach may provide valuable insight into designing programmable mesoporous mesocrystals by controlling the oriented assembly of monomicelle building blocks. 2 2 2 2 2 2 −1 −1
dc.description.peerreviewedYes
dc.languageen
dc.publisherElsevier BV
dc.relation.ispartofpagefrom100081
dc.relation.ispartofissue7
dc.relation.ispartofjournalCell Reports Physical Science
dc.relation.ispartofvolume1
dc.subject.fieldofresearchNanotechnology
dc.subject.fieldofresearchcode4018
dc.titleBranched Mesoporous TiO2 Mesocrystals by Epitaxial Assembly of Micelles for Photocatalysis
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationZhang, P; Tian, Z; Hung, CT; Liu, Y; Jia, B; Lan, K; Kong, B; Huang, F; Mai, L; Zhao, D, Branched Mesoporous TiO2 Mesocrystals by Epitaxial Assembly of Micelles for Photocatalysis, Cell Reports Physical Science, 2020, 1 (7), pp. 100081
dcterms.licensehttps://creativecommons.org/licenses/by/4.0/
dc.date.updated2021-04-08T00:42:33Z
dc.description.versionVersion of Record (VoR)
gro.rights.copyright© The Author(s) 2020. This is an Open Access article distributed under the terms of the Creative Commons Attribution 4.0 International License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
gro.hasfulltextFull Text
gro.griffith.authorZhao, Dongyuan


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