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dc.contributor.authorHorn, MR
dc.contributor.authorSingh, A
dc.contributor.authorAlomari, S
dc.contributor.authorGoberna-Ferrón, S
dc.contributor.authorBenages-Vilau, R
dc.contributor.authorChodankar, N
dc.contributor.authorMotta, N
dc.contributor.authorOstrikov, K
dc.contributor.authorMacleod, J
dc.contributor.authorSonar, P
dc.contributor.authorGomez-Romero, P
dc.contributor.authorDubal, D
dc.date.accessioned2021-05-06T00:14:26Z
dc.date.available2021-05-06T00:14:26Z
dc.date.issued2021
dc.identifier.issn1754-5692
dc.identifier.doi10.1039/d0ee03407j
dc.identifier.urihttp://hdl.handle.net/10072/404188
dc.description.abstractPolyoxometalates (POMs) represent a class of nanomaterials, which hold enormous promise for a range of energy-related applications. Their promise is owing to their “special” structure that gives POMs a truly unique ability to control redox reactions in energy conversion and storage. One such amazing capability is their large number of redox active sites that arises from the complex three-dimensional cluster of metal-oxide ions linked together by oxygen atoms. Here, a critical review on how POMs emerged from being molecular clusters for fundamental studies, to next-generation materials for energy applications is provided. We highlight how exploiting the versatility and activity of these molecules can lead to improved performance in energy devices such as supercapacitors and batteries, and in energy catalyst applications. The potential of POMs across numerous fields is systematically outlined by investigating structure–property–performance relationships and the determinant factors for energy systems. Finally, the challenges and opportunities for this class of materials with respect to addressing our pressing energy-related concerns are identified.
dc.description.peerreviewedYes
dc.languageen
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.ispartofpagefrom1652
dc.relation.ispartofpageto1700
dc.relation.ispartofissue4
dc.relation.ispartofjournalEnergy and Environmental Science
dc.relation.ispartofvolume14
dc.subject.fieldofresearchEnvironmental Nanotechnology
dc.subject.fieldofresearchcode100701
dc.titlePolyoxometalates (POMs): From electroactive clusters to energy materials
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationHorn, MR; Singh, A; Alomari, S; Goberna-Ferrón, S; Benages-Vilau, R; Chodankar, N; Motta, N; Ostrikov, K; Macleod, J; Sonar, P; Gomez-Romero, P; Dubal, D, Polyoxometalates (POMs): From electroactive clusters to energy materials, Energy and Environmental Science, 2021, 14 (4), pp. 1652-1700
dc.date.updated2021-05-05T23:15:52Z
dc.description.versionAccepted Manuscript (AM)
gro.rights.copyright© 2021 Royal Society of Chemistry. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal website for access to the definitive, published version.
gro.hasfulltextFull Text
gro.griffith.authorSonar, Prashant
gro.griffith.authorOstrikov, Ken
gro.griffith.authorPannu, Amandeep Singh S.


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