dc.contributor.author | Smith, Graham | |
dc.contributor.author | Wermuth, Urs D. | |
dc.date.accessioned | 2022-07-06T07:34:01Z | |
dc.date.available | 2022-07-06T07:34:01Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2056-9890 | |
dc.identifier.doi | 10.1107/S2056989016006691 | |
dc.identifier.uri | http://hdl.handle.net/10072/405443 | |
dc.description.abstract | In the structure of the brucinium salt of 4-aminophenylarsonic acid (p-arsanilic acid), systematically 2,3-dimethoxy-10-oxostrychnidinium 4-aminophenylarsonate tetrahydrate, (C23H27N2O4)[As(C6H7N)O2(OH)]·4H2O, the brucinium cations form the characteristic undulating and overlapping head-to-tail layered brucine substructures packed along [010]. The arsanilate anions and the water molecules of solvation are accommodated between the layers and are linked to them through a primary cation N—H⋯O(anion) hydrogen bond, as well as through water O—H⋯O hydrogen bonds to brucinium and arsanilate ions as well as bridging water O-atom acceptors, giving an overall three-dimensional network structure. | |
dc.description.peerreviewed | Yes | |
dc.language | English | |
dc.publisher | International Union of Crystallography | |
dc.relation.ispartofpagefrom | 751 | |
dc.relation.ispartofpageto | 755 | |
dc.relation.ispartofissue | 5 | |
dc.relation.ispartofjournal | Acta Cystallographica Section E: Crystallographic Communications | |
dc.relation.ispartofvolume | E72 | |
dc.subject.fieldofresearch | Physical sciences | |
dc.subject.fieldofresearch | Analytical chemistry | |
dc.subject.fieldofresearch | Crystallography | |
dc.subject.fieldofresearchcode | 51 | |
dc.subject.fieldofresearchcode | 3401 | |
dc.subject.fieldofresearchcode | 340202 | |
dc.subject.keywords | Science & Technology | |
dc.subject.keywords | crystal structure | |
dc.subject.keywords | brucinium salts | |
dc.title | Crystal structure and hydrogen bonding in the water-stabilized proton-transfer salt brucinium 4-aminophenylarsonate tetrahydrate | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dcterms.bibliographicCitation | Smith, G; Wermuth, UD, Crystal structure and hydrogen bonding in the water-stabilized proton-transfer salt brucinium 4-aminophenylarsonate tetrahydrate, Acta Cystallographica Section E: Crystallographic Communications, 2016, 72 (5), pp. 751-755 | |
dcterms.dateAccepted | 2016-04-19 | |
dcterms.license | https://creativecommons.org/licenses/by/4.0/ | |
dc.date.updated | 2021-06-29T02:34:00Z | |
dc.description.version | Version of Record (VoR) | |
gro.rights.copyright | © The Author(s) 2016. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. | |
gro.hasfulltext | Full Text | |
gro.griffith.author | Wermuth, Urs D. | |