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dc.contributor.authorSmith, Graham
dc.contributor.authorWermuth, Urs D.
dc.date.accessioned2022-07-06T07:34:01Z
dc.date.available2022-07-06T07:34:01Z
dc.date.issued2016
dc.identifier.issn2056-9890
dc.identifier.doi10.1107/S2056989016006691
dc.identifier.urihttp://hdl.handle.net/10072/405443
dc.description.abstractIn the structure of the brucinium salt of 4-amino­phenyl­arsonic acid (p-arsanilic acid), systematically 2,3-dimeth­oxy-10-oxostrychnidinium 4-amino­phenyl­ar­son­ate tetra­hydrate, (C23H27N2O4)[As(C6H7N)O2(OH)]·4H2O, the brucinium cations form the characteristic undulating and overlapping head-to-tail layered brucine substructures packed along [010]. The arsanilate anions and the water mol­ecules of solvation are accommodated between the layers and are linked to them through a primary cation N—H⋯O(anion) hydrogen bond, as well as through water O—H⋯O hydrogen bonds to brucinium and arsanilate ions as well as bridging water O-atom acceptors, giving an overall three-dimensional network structure.
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherInternational Union of Crystallography
dc.relation.ispartofpagefrom751
dc.relation.ispartofpageto755
dc.relation.ispartofissue5
dc.relation.ispartofjournalActa Cystallographica Section E: Crystallographic Communications
dc.relation.ispartofvolumeE72
dc.subject.fieldofresearchPhysical sciences
dc.subject.fieldofresearchAnalytical chemistry
dc.subject.fieldofresearchCrystallography
dc.subject.fieldofresearchcode51
dc.subject.fieldofresearchcode3401
dc.subject.fieldofresearchcode340202
dc.subject.keywordsScience & Technology
dc.subject.keywordscrystal structure
dc.subject.keywordsbrucinium salts
dc.titleCrystal structure and hydrogen bonding in the water-stabilized proton-transfer salt brucinium 4-amino­phenyl­arsonate tetra­hydrate
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationSmith, G; Wermuth, UD, Crystal structure and hydrogen bonding in the water-stabilized proton-transfer salt brucinium 4-amino­phenyl­arsonate tetra­hydrate, Acta Cystallographica Section E: Crystallographic Communications, 2016, 72 (5), pp. 751-755
dcterms.dateAccepted2016-04-19
dcterms.licensehttps://creativecommons.org/licenses/by/4.0/
dc.date.updated2021-06-29T02:34:00Z
dc.description.versionVersion of Record (VoR)
gro.rights.copyright© The Author(s) 2016. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
gro.hasfulltextFull Text
gro.griffith.authorWermuth, Urs D.


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