dc.contributor.author | Zhou, Peng | |
dc.contributor.author | Zhang, Qinghua | |
dc.contributor.author | Chao, Yuguang | |
dc.contributor.author | Wang, Liang | |
dc.contributor.author | Li, Yiju | |
dc.contributor.author | Chen, Hui | |
dc.contributor.author | Gu, Lin | |
dc.contributor.author | Guo, Shaojun | |
dc.date.accessioned | 2021-06-30T02:55:36Z | |
dc.date.available | 2021-06-30T02:55:36Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 2451-9294 | en_US |
dc.identifier.doi | 10.1016/j.chempr.2021.01.007 | en_US |
dc.identifier.uri | http://hdl.handle.net/10072/405479 | |
dc.description.abstract | Photocatalytic co-production of high value-added multicarbon compounds and hydrogen from renewable bioethanol is an environmental and long-term approach to industrial activities and remains a great challenge because of the difficulty in bioethanol dehydrogenation. Guided by first-principle simulation, we first synthesized a partially reduced Pd–P3 single atom (PdPSA) on CdS nanorods with an unoccupied hybrid state of Pd 4d and P 3p via both metal-support interaction effect and Pd–P coordination effect. This unique electronic structure of PdPSA is totally different from highly reduced S-coordinated Pd single atoms or nanoparticles and allows PdPSA-CdS to exhibit a visible-light photocatalytic activity of 35.1 mmol g−1 h−1 for the co-production of high-value-added 1,1-diethoxyethane and H2 with a selectivity of 100%. Mechanism studies revealed that the unoccupied hybrid states of Pd 4d and P 3p in PdPSA not only greatly promoted the dehydrogenation of ethanol but also promised PdPSA with a high H2-production activity. | en_US |
dc.description.peerreviewed | Yes | en_US |
dc.language | en | en_US |
dc.publisher | Elsevier BV | en_US |
dc.relation.ispartofpagefrom | 1033 | en_US |
dc.relation.ispartofpageto | 1049 | en_US |
dc.relation.ispartofissue | 4 | en_US |
dc.relation.ispartofjournal | Chem | en_US |
dc.relation.ispartofvolume | 7 | en_US |
dc.subject.fieldofresearch | Macromolecular and Materials Chemistry | en_US |
dc.subject.fieldofresearchcode | 0303 | en_US |
dc.title | Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound | en_US |
dc.type | Journal article | en_US |
dc.type.description | C1 - Articles | en_US |
dcterms.bibliographicCitation | Zhou, P; Zhang, Q; Chao, Y; Wang, L; Li, Y; Chen, H; Gu, L; Guo, S, Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound, Chem, 2021, 7 (4), pp. 1033-1049 | en_US |
dc.date.updated | 2021-06-29T04:33:34Z | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Wang, Liang | |