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dc.contributor.authorL. Cosgrove, Kelly
dc.contributor.authorP. McGeary, Ross
dc.date.accessioned2017-05-03T15:43:46Z
dc.date.available2017-05-03T15:43:46Z
dc.date.issued2009
dc.date.modified2011-08-31T07:19:43Z
dc.identifier.issn0936-5214
dc.identifier.doi10.1055/s-0029-1217382
dc.identifier.urihttp://hdl.handle.net/10072/40559
dc.description.abstractMixed ortho esters derived from allylic alcohols undergo methanol elimination in the presence of triisobutylaluminium (TIBAL) at room temperature to form mixed ketene acetals. TIBAL then promotes immediate Claisen rearrangement of these intermediates, and subsequent reduction of the ester products, to give unsaturated ?,d-primary alcohols in a convenient, one-pot procedure.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherGeorg Thieme Verlag
dc.publisher.placeGermany
dc.relation.ispartofstudentpublicationY
dc.relation.ispartofpagefrom1749
dc.relation.ispartofpageto1752
dc.relation.ispartofissue11
dc.relation.ispartofjournalSynlett
dc.relation.ispartofvolume2009
dc.rights.retentionY
dc.subject.fieldofresearchOrganic Chemical Synthesis
dc.subject.fieldofresearchMedicinal and Biomolecular Chemistry
dc.subject.fieldofresearchOrganic Chemistry
dc.subject.fieldofresearchcode030503
dc.subject.fieldofresearchcode0304
dc.subject.fieldofresearchcode0305
dc.titleA Convenient Triisobutylaluminium (TIBAL)-Promoted Johnson-Claisen Approach to γ,δ-Unsaturated Alcohols
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2009
gro.hasfulltextNo Full Text
gro.griffith.authorCosgrove, Kelly


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