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dc.contributor.authorMiao, W
dc.contributor.authorLiu, Y
dc.contributor.authorWang, D
dc.contributor.authorDu, N
dc.contributor.authorYe, Z
dc.contributor.authorHou, Y
dc.contributor.authorMao, S
dc.contributor.authorOstrikov, K
dc.date.accessioned2021-07-01T23:59:48Z
dc.date.available2021-07-01T23:59:48Z
dc.date.issued2021
dc.identifier.issn1385-8947
dc.identifier.doi10.1016/j.cej.2021.130250
dc.identifier.urihttp://hdl.handle.net/10072/405602
dc.description.abstractTransition-metal and nitrogen co-doped carbon-based catalysts receive much attention in peroxymonosulfate (PMS) activation. However, the contribution of doped metal and the kinetic mechanisms of the emerging nonradical pathways especially enabled by reactive singlet oxygen species remain unclear. Herein, we report Fe-N-co-doped carbon-based catalysts (FeCNx) for peroxymonosulfate activation. The catalysts achieve fast removal of a broad spectrum of organic pollutants in a wide pH range without the common Fe leaching. Both catalyst surface-activated PMS complex (catalyst-PMS*), surface-bound radicals, and singlet oxygen are identified. The new mechanism is enabled by the Fe-Nx single-atomic-site that enhances the adsorption of PMS and facilitates the formation of catalyst-PMS*. The formation route of singlet oxygen species is elucidated for the first time for Fe, N-co-doped carbon-based catalysts with density functional theory simulation. This study reveals the intrinsic role of Fe-Nx site in catalysts and provides new insights into the origin and kinetics of non-radical pathways for peroxymonosulfate activation.
dc.description.peerreviewedYes
dc.languageen
dc.publisherElsevier BV
dc.relation.ispartofpagefrom130250
dc.relation.ispartofjournalChemical Engineering Journal
dc.relation.ispartofvolume423
dc.subject.fieldofresearchChemical Engineering
dc.subject.fieldofresearchCivil Engineering
dc.subject.fieldofresearchEnvironmental Engineering
dc.subject.fieldofresearchcode0904
dc.subject.fieldofresearchcode0905
dc.subject.fieldofresearchcode0907
dc.titleThe role of Fe-Nx single-atom catalytic sites in peroxymonosulfate activation: Formation of surface-activated complex and non-radical pathways
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationMiao, W; Liu, Y; Wang, D; Du, N; Ye, Z; Hou, Y; Mao, S; Ostrikov, K, The role of Fe-Nx single-atom catalytic sites in peroxymonosulfate activation: Formation of surface-activated complex and non-radical pathways, Chemical Engineering Journal, 2021, 423, pp. 130250
dc.date.updated2021-07-01T23:57:13Z
gro.hasfulltextNo Full Text
gro.griffith.authorOstrikov, Ken


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