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dc.contributor.authorYang, Tianyu
dc.contributor.authorWei, Lijuan
dc.contributor.authorJing, Lingyan
dc.contributor.authorLiang, Jifen
dc.contributor.authorZhang, Xiaoming
dc.contributor.authorTang, Min
dc.contributor.authorMonteiro, Michael J
dc.contributor.authorChen, Ying Ian
dc.contributor.authorWang, Yong
dc.contributor.authorGu, Sai
dc.contributor.authorZhao, Dongyuan
dc.contributor.authorYang, Hengquan
dc.contributor.authorLiu, Jian
dc.contributor.authorLu, GQ Max
dc.date.accessioned2021-07-19T06:26:32Z
dc.date.available2021-07-19T06:26:32Z
dc.date.issued2017
dc.identifier.issn1433-7851
dc.identifier.doi10.1002/anie.201701640
dc.identifier.urihttp://hdl.handle.net/10072/406134
dc.description.abstractThere is a strong desire to design and synthesize catalysts that assemble at the oil–water interface to improve the efficiency of biphasic reactions. Anisotropic dumbbell-shaped bi-component mesoporous carbon–organosilica Janus particles with asymmetric wettability are synthesized through a one-step compartmentalized growth of a mesoporous organosilica sphere attached to a mesoporous resorcinol–formaldehyde (RF) sphere. A library was prepared of tunable Janus particles possessing diverse hollow structures with various functionalities. As a proof of concept, the Janus particle-derived catalyst can assemble at the oil–water interface to stabilize Pickering emulsions. Owing to the increased reaction interface area, the Janus catalyst exhibits a more than three-fold increase in catalytic efficiency compared to the Pt loaded carbon sphere catalyst in aqueous hydrogenation reactions.
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherJohn Wiley & Sons
dc.relation.ispartofpagefrom8459
dc.relation.ispartofpageto8463
dc.relation.ispartofissue29
dc.relation.ispartofjournalAngewandte Chemie International Edition
dc.relation.ispartofvolume56
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.subject.keywordsScience & Technology
dc.subject.keywordsPhysical Sciences
dc.subject.keywordsChemistry, Multidisciplinary
dc.subject.keywordsChemistry
dc.subject.keywordshydrogenation
dc.titleDumbbell-shaped bi-component mesoporous Janus solid nanoparticles for biphasic interface catalysis
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationYang, T; Wei, L; Jing, L; Liang, J; Zhang, X; Tang, M; Monteiro, MJ; Chen, YI; Wang, Y; Gu, S; Zhao, D; Yang, H; Liu, J; Lu, GQM, Dumbbell-shaped bi-component mesoporous Janus solid nanoparticles for biphasic interface catalysis, Angewandte Chemie International Edition, 2017, 56 (29), pp. 8459-8463
dc.date.updated2021-07-19T06:19:19Z
gro.hasfulltextNo Full Text
gro.griffith.authorZhao, Dongyuan
gro.griffith.authorMonteiro, Michael J.


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