Tuneable fluidics within graphene nanogaps for water purification and energy storage
Author(s)
Bo, Zheng
Tian, Yilei
Han, Zhao Jun
Wu, Shenghao
Zhang, Shuo
Yan, Jianhua
Cen, Kefa
Ostrikov, Kostya Ken
Griffith University Author(s)
Year published
2017
Metadata
Show full item recordAbstract
Precise control of liquid-solid interactions within sub-micrometer spaces is critical to maximize the active surface areas in porous materials, yet is challenging because of the limited liquid penetration. Here we discover an effective, dry-climate natural plant-inspired approach to guide water into sub-micrometer graphene microwells (Sub-μGWs) and to tune the transition from the hydrophobic to superhydrophilic states. Dry plasma texturing of Sub-μGWs by graphene 'nano-flaps' which adjust the tilt and density upon controlled liquid evaporation leads to controlled and stable sub-micrometer-scale surface modification and ...
View more >Precise control of liquid-solid interactions within sub-micrometer spaces is critical to maximize the active surface areas in porous materials, yet is challenging because of the limited liquid penetration. Here we discover an effective, dry-climate natural plant-inspired approach to guide water into sub-micrometer graphene microwells (Sub-μGWs) and to tune the transition from the hydrophobic to superhydrophilic states. Dry plasma texturing of Sub-μGWs by graphene 'nano-flaps' which adjust the tilt and density upon controlled liquid evaporation leads to controlled and stable sub-micrometer-scale surface modification and variable wettability in a wide range. This effect helps capture Au nanoparticles on the Sub-μGW surfaces as a proof-of-principle water purification platform and tune the charge-storage capacity and frequency response of Sub-μGW-based supercapacitors without altering the Sub-μGW backbones. The outcomes may be extended into diverse materials and solutions thus opening new opportunities for next-generation devices, systems and applications.
View less >
View more >Precise control of liquid-solid interactions within sub-micrometer spaces is critical to maximize the active surface areas in porous materials, yet is challenging because of the limited liquid penetration. Here we discover an effective, dry-climate natural plant-inspired approach to guide water into sub-micrometer graphene microwells (Sub-μGWs) and to tune the transition from the hydrophobic to superhydrophilic states. Dry plasma texturing of Sub-μGWs by graphene 'nano-flaps' which adjust the tilt and density upon controlled liquid evaporation leads to controlled and stable sub-micrometer-scale surface modification and variable wettability in a wide range. This effect helps capture Au nanoparticles on the Sub-μGW surfaces as a proof-of-principle water purification platform and tune the charge-storage capacity and frequency response of Sub-μGW-based supercapacitors without altering the Sub-μGW backbones. The outcomes may be extended into diverse materials and solutions thus opening new opportunities for next-generation devices, systems and applications.
View less >
Journal Title
Nanoscale Horizons
Volume
2
Issue
2
Subject
Nanomaterials
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Nanoscience & Nanotechnology