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dc.contributor.authorPalaniappan, N
dc.contributor.authorCole, Ivan S
dc.contributor.authorKuznetsov, A
dc.contributor.authorThomas, KR Justin
dc.contributor.authorBalasubramanian, K
dc.contributor.authorManickam, Sivakumar
dc.date.accessioned2021-10-06T01:21:04Z
dc.date.available2021-10-06T01:21:04Z
dc.date.issued2021
dc.identifier.issn2046-2069
dc.identifier.doi10.1039/d1ra03495b
dc.identifier.urihttp://hdl.handle.net/10072/408605
dc.description.abstractMagnesium alloys are broadly used worldwide in various applications; however, the serious disadvantage of these alloys are subject to corrosion and in aggressive/corrosive environments. A coating containing gadolinium-based composite materials can increase the alloy protection by strong electron transfer between the host alloy and the lanthanide-containing protective layer. This investigation aims to develop a Gd nanorod functionalised graphene oxide material as a corrosion inhibition barrier on the Mg alloy surface. The obtained functional materials were characterised by various spectroscopy techniques. The corrosion inhibition and composite material stability were studied by the electrochemical methods. The electrochemical stability was shown to increase with the applied current. The hydrogen evolution constantly increased and the corrosion inhibition significantly improved. Also, the computational studies of the material were performed, and their results support the experimental findings. Overall, the resultant composite material's corrosion resistance and cyclic stability are improved, and it could be used as a sodium-ion battery cathode material due to its high reversibility. This journal is
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofpagefrom22095
dc.relation.ispartofpageto22105
dc.relation.ispartofissue36
dc.relation.ispartofjournalRSC Advances
dc.relation.ispartofvolume11
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.subject.keywordsScience & Technology
dc.subject.keywordsPhysical Sciences
dc.subject.keywordsChemistry, Multidisciplinary
dc.subject.keywordsChemistry
dc.subject.keywordsCOMPACT EFFECTIVE POTENTIALS
dc.titleExperimental and DFT studies of gadolinium decorated graphene oxide materials for their redox properties and as a corrosion inhibition barrier layer on Mg AZ13 alloy in a 3.5% NaCl environment
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationPalaniappan, N; Cole, IS; Kuznetsov, A; Thomas, KRJ; Balasubramanian, K; Manickam, S, Experimental and DFT studies of gadolinium decorated graphene oxide materials for their redox properties and as a corrosion inhibition barrier layer on Mg AZ13 alloy in a 3.5% NaCl environment, RSC Advances, 2021, 11 (36), pp. 22095-22105
dcterms.licensehttps://creativecommons.org/licenses/by/4.0/
dc.date.updated2021-10-06T01:18:52Z
dc.description.versionVersion of Record (VoR)
gro.rights.copyright© The Author(s) 2021. This is an Open Access article distributed under the terms of the Creative Commons Attribution 4.0 International License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
gro.hasfulltextFull Text
gro.griffith.authorCole, Ivan


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