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dc.contributor.authorZhao, Qingzhou
dc.contributor.authorWang, Yanfen
dc.contributor.authorXu, Zhihong
dc.contributor.authorYu, Zhisheng
dc.date.accessioned2021-10-11T04:13:11Z
dc.date.available2021-10-11T04:13:11Z
dc.date.issued2021
dc.identifier.issn1944-3994
dc.identifier.doi10.5004/dwt.2021.27011
dc.identifier.urihttp://hdl.handle.net/10072/408790
dc.description.abstractRecent interests in aqueous cadmium and lead removal has been driven by the rapid progress of the adsorption on biochar, which is an environmentally friendly adsorbent with high effectiveness. The biochar was prepared from pyrolysis of straw under 400°C and characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller, Fourier-transform infrared spectroscopy and Raman spectra analysis. The batch experiments were performed to investigate the capacity and mechanism of the adsorption. The kinetic of either Cd(II) or Pb(II) adsorption fitted in both pseudo-first-order kinetic model and pseudo-second-order kinetic model. The adsorption capacity increased rapidly in the initial 30 min and then slowed down until the plateau after 80 min. Both the capacity of the Cd(II) and Pb(II) removal increased with pH value elevation at the relatively low pH range while the Pb(II) adsorption capacity decreased with pH value elevation in the range of 8.5–11.0. Nevertheless, these adsorptions were independent of the ionic strength. Either Cd(II) or Pb(II) adsorption process fitted the Langmuir model and Freundlich model well. The thermodynamic data demonstrated the cadmium adsorption on biochar as the endothermic and spontaneous reaction with the ΔH° = 21.31, ΔS° = 136.77 and ΔG° < 0 at 293, 313 and 333 K. The lead adsorption exhibited similar natures with ΔH° = 17.20, ΔS° = 127.92 and ΔG° < 0. Thus, biochar would be a green material as the potential adsorbent for the cadmium and lead removal in aqueous solutions.
dc.description.peerreviewedYes
dc.languageEnglish
dc.publisherDesalination Publications
dc.relation.ispartofpagefrom199
dc.relation.ispartofpageto210
dc.relation.ispartofjournalDesalination and Water Treatment
dc.relation.ispartofvolume220
dc.subject.fieldofresearchChemical engineering
dc.subject.fieldofresearchCivil engineering
dc.subject.fieldofresearchEnvironmental engineering
dc.subject.fieldofresearchcode4004
dc.subject.fieldofresearchcode4005
dc.subject.fieldofresearchcode4011
dc.subject.keywordsScience & Technology
dc.subject.keywordsPhysical Sciences
dc.subject.keywordsEngineering, Chemical
dc.subject.keywordsWater Resources
dc.titleRemoval mechanisms of Cd(II) and Pb(II) from aqueous solutions using straw biochar: batch study, Raman and X-ray photoelectron spectroscopy techniques
dc.typeJournal article
dc.type.descriptionC1 - Articles
dcterms.bibliographicCitationZhao, Q; Wang, Y; Xu, Z; Yu, Z, Removal mechanisms of Cd(II) and Pb(II) from aqueous solutions using straw biochar: batch study, Raman and X-ray photoelectron spectroscopy techniques, Desalination and Water Treatment, 2021, 220, pp. 199-210
dc.date.updated2021-10-11T04:07:19Z
gro.hasfulltextNo Full Text
gro.griffith.authorXu, Zhihong
gro.griffith.authorZhao, Qingzhou


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