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dc.contributor.authorSu, Lina
dc.contributor.authorZhang, Yin
dc.contributor.authorQiu, Xueying
dc.contributor.authorHan, Jianyu
dc.contributor.authorTang, Zhiyong
dc.date.accessioned2021-10-12T03:14:54Z
dc.date.available2021-10-12T03:14:54Z
dc.date.issued2020
dc.identifier.issn1001-604X
dc.identifier.doi10.1002/cjoc.202000463
dc.identifier.urihttp://hdl.handle.net/10072/408892
dc.description.abstractIn this work, important commercial pharmaceutical intermediates, phenylpropionic acid compounds, are successfully obtained by catalyzing the reaction of carbon dioxide with phenyl halides using MOF-5, a typical metal-organic framework (MOF) material. The influence of temperature, pressure, catalyst type and light on the reaction is investigated, and a 90.3% selectivity towards fluorophenylpropionic acid is reached. Significantly, the catalysts are effective for varied benzyl compounds containing different substituent groups. The catalysts are stable and remain active after three cycles.
dc.languageEnglish
dc.publisherWiley
dc.relation.ispartofpagefrom312
dc.relation.ispartofpageto316
dc.relation.ispartofissue2
dc.relation.ispartofjournalChinese Journal of Chemistry
dc.relation.ispartofvolume39
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.subject.keywordsScience & Technology
dc.subject.keywordsPhysical Sciences
dc.subject.keywordsChemistry, Multidisciplinary
dc.subject.keywordsChemistry
dc.subject.keywordsMetal&#8208
dc.titlePhotocatalytic Carboxylation of Phenyl Halides with CO2 by Metal-Organic Frameworks Materials
dc.typeJournal article
dcterms.bibliographicCitationSu, L; Zhang, Y; Qiu, X; Han, J; Tang, Z, Photocatalytic Carboxylation of Phenyl Halides with CO2 by Metal-Organic Frameworks Materials, Chinese Journal of Chemistry, 2020, 39 (2), pp. 312-316
dc.date.updated2021-10-12T03:13:49Z
gro.hasfulltextNo Full Text
gro.griffith.authorTang, Zhiyong


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