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dc.contributor.authorWu, Qilong
dc.contributor.authorGao, Jin
dc.contributor.authorFeng, Jianrui
dc.contributor.authorLiu, Qian
dc.contributor.authorZhou, Yunjie
dc.contributor.authorZhang, Shengbo
dc.contributor.authorNie, Manxiu
dc.contributor.authorLiu, Yang
dc.contributor.authorZhao, Jiongpeng
dc.contributor.authorLiu, Fuchen
dc.contributor.authorZhong, Jun
dc.contributor.authorKang, Zhenhui
dc.date.accessioned2022-05-09T02:31:07Z
dc.date.available2022-05-09T02:31:07Z
dc.date.issued2020
dc.identifier.issn2050-7488en_US
dc.identifier.doi10.1039/c9ta11473den_US
dc.identifier.urihttp://hdl.handle.net/10072/414391
dc.description.abstractControlling interface gas adsorption properties of carbon materials is a prerequisite for exploiting efficient metal-free electrocatalysts but it is usually ignored. Herein, we fabricate a hierarchical porous carbon electrocatalyst with defect (DHPC) by carbon thermal reaction, which shows good CO2RR selectivity and stability. The experimental results indicated that the carbon defect might be the active center for efficient CO2RR performance because it can serve as a Lewis base center and provide an appropriate CO2-chemisorption energy. Moreover, X-ray absorption spectroscopy (XAS) results demonstrated that the carbon defect can induce a reversible carbon–carbon interface with CO2 gas molecule, which would be further strengthened under an applied bias. Besides, the 13CO2 isotope labelling experiment and density functional theory calculations further confirmed that the high CO2RR performance of DHPC comes from its intrinsic defect sites. This study not only provides a new avenue and concept to design CO2RR electrocatalysts but also, to some extent, indicates a possible catalytic mechanism for carbon defect-based electrocatalysts.en_US
dc.description.peerreviewedYesen_US
dc.languageEnglishen_US
dc.publisherRoyal Society of Chemistry Publishingen_US
dc.relation.ispartofpagefrom1205en_US
dc.relation.ispartofpageto1211en_US
dc.relation.ispartofissue3en_US
dc.relation.ispartofjournalJournal of Materials Chemistry Aen_US
dc.relation.ispartofvolume8en_US
dc.subject.fieldofresearchMacromolecular and materials chemistryen_US
dc.subject.fieldofresearchMaterials engineeringen_US
dc.subject.fieldofresearchcode3403en_US
dc.subject.fieldofresearchcode4016en_US
dc.subject.keywordsScience & Technologyen_US
dc.subject.keywordsPhysical Sciencesen_US
dc.subject.keywordsTechnologyen_US
dc.subject.keywordsChemistry, Physicalen_US
dc.subject.keywordsEnergy & Fuelsen_US
dc.titleA CO2 adsorption dominated carbon defect-based electrocatalyst for efficient carbon dioxide reductionen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Articlesen_US
dcterms.bibliographicCitationWu, Q; Gao, J; Feng, J; Liu, Q; Zhou, Y; Zhang, S; Nie, M; Liu, Y; Zhao, J; Liu, F; Zhong, J; Kang, Z, A CO2 adsorption dominated carbon defect-based electrocatalyst for efficient carbon dioxide reduction, Journal of Materials Chemistry A, 2020, 8 (3), pp. 1205-1211en_US
dc.date.updated2022-05-06T05:52:06Z
gro.hasfulltextNo Full Text
gro.griffith.authorWu, Qi-Long


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