([eta]6-Isopropyl N-phenylcarbamate)([eta]5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate acetone monosolvate
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The title complex, [Ru(C10H15)(C10H13NO2)](C24H20B)烳H6O, is related to the analogous O-methyl complex. The average Ru-C distance to the pentamethylcyclopentadienyl (Cp*) group is 2.19 (3) Ŭ and 2.21 (1) Što the ortho, meta and para C atoms of the arene ring. The Ru-Cipso bond length of 2.272 (3) Šis significantly longer, reflecting movement of the Ru atom away from the C atoms with electronegative substituents attached. The amide H atom in the cation forms an intermolecular N-H...O hydrogen bond with the carbonyl O atom of the acetone solvent molecule. A C-H...O interaction also occurs.
Acta Crystallographica. Section E: Structure Reports Online
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Structural Chemistry and Spectroscopy