Porous Indium Nanocrystals on Conductive Carbon Nanotube Networks for High-Performance CO2-to-Formate Electrocatalytic Conversion

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Author(s)
Xiao, L
Zhou, R
Zhang, T
Wang, X
Zhou, R
Cullen, PJ
Ostrikov, K
Griffith University Author(s)
Year published
2023
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Ever-increasing emissions of anthropogenic carbon dioxide (CO2) cause global environmental and climate challenges. Inspired by biological photosynthesis, developing effective strategies NeuNlto up-cycle CO2 into high-value organics is crucial. Electrochemical CO2 reduction reaction (CO2RR) is highly promising to convert CO2 into economically viable carbon-based chemicals or fuels under mild process conditions. Herein, mesoporous indium supported on multi-walled carbon nanotubes (mp-In@MWCNTs) is synthesized via a facile wet chemical method. The mp-In@MWCNTs electrocatalysts exhibit high CO2RR performance in reducing CO2 into ...
View more >Ever-increasing emissions of anthropogenic carbon dioxide (CO2) cause global environmental and climate challenges. Inspired by biological photosynthesis, developing effective strategies NeuNlto up-cycle CO2 into high-value organics is crucial. Electrochemical CO2 reduction reaction (CO2RR) is highly promising to convert CO2 into economically viable carbon-based chemicals or fuels under mild process conditions. Herein, mesoporous indium supported on multi-walled carbon nanotubes (mp-In@MWCNTs) is synthesized via a facile wet chemical method. The mp-In@MWCNTs electrocatalysts exhibit high CO2RR performance in reducing CO2 into formate. An outstanding activity (current density −78.5 mA cm−2), high conversion efficiency (Faradaic efficiency of formate over 90%), and persistent stability (~30 h) for selective CO2-to-formate conversion are observed. The outstanding CO2RR process performance is attributed to the unique structures with mesoporous surfaces and a conductive network, which promote the adsorption and desorption of reactants and intermediates while improving electron transfer. These findings provide guiding principles for synthesizing conductive metal-based electrocatalysts for high-performance CO2 conversion.
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View more >Ever-increasing emissions of anthropogenic carbon dioxide (CO2) cause global environmental and climate challenges. Inspired by biological photosynthesis, developing effective strategies NeuNlto up-cycle CO2 into high-value organics is crucial. Electrochemical CO2 reduction reaction (CO2RR) is highly promising to convert CO2 into economically viable carbon-based chemicals or fuels under mild process conditions. Herein, mesoporous indium supported on multi-walled carbon nanotubes (mp-In@MWCNTs) is synthesized via a facile wet chemical method. The mp-In@MWCNTs electrocatalysts exhibit high CO2RR performance in reducing CO2 into formate. An outstanding activity (current density −78.5 mA cm−2), high conversion efficiency (Faradaic efficiency of formate over 90%), and persistent stability (~30 h) for selective CO2-to-formate conversion are observed. The outstanding CO2RR process performance is attributed to the unique structures with mesoporous surfaces and a conductive network, which promote the adsorption and desorption of reactants and intermediates while improving electron transfer. These findings provide guiding principles for synthesizing conductive metal-based electrocatalysts for high-performance CO2 conversion.
View less >
Journal Title
Energy and Environmental Materials
Copyright Statement
© 2023 The Authors. Energy & Environmental Materials published by
John Wiley & Sons Australia, Ltd on behalf of Zhengzhou University. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Note
This publication has been entered in Griffith Research Online as an advanced online version.
Subject
Chemical engineering
Environmental engineering