Poly[aqua(μ3-2-hydroxy-5-nitrobenzoato- κ3O1:O1':O2)rubidium]
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Author(s)
Smith, Graham
Wermuth, Urs D
Williams, Michael L
Year published
2011
Metadata
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In the structure of title compound, [Rb(C7H4NO5)(H2O)]n, the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO4 complex centres bridged by the carboxylate groups of the 5-nitrosalicylate ligands. The coordination about each Rb atom is completed by a monodentate water molecule and a phenolic O-atom donor which gives a bridging extension [Rb-O range = 3.116 (7)-3.135 (5) A ࠝ. The polymeric structure is stabilized by intermolecular water O- H...Ocarboxylate hydrogen bonds and weak inter-ring pi-pi interactions [minimum ring centroid separation = 3.620 (4) A ࠝ. An intramolecular O-H...O hydrogen ...
View more >In the structure of title compound, [Rb(C7H4NO5)(H2O)]n, the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO4 complex centres bridged by the carboxylate groups of the 5-nitrosalicylate ligands. The coordination about each Rb atom is completed by a monodentate water molecule and a phenolic O-atom donor which gives a bridging extension [Rb-O range = 3.116 (7)-3.135 (5) A ࠝ. The polymeric structure is stabilized by intermolecular water O- H...Ocarboxylate hydrogen bonds and weak inter-ring pi-pi interactions [minimum ring centroid separation = 3.620 (4) A ࠝ. An intramolecular O-H...O hydrogen bond between phenol and carboxylate groups is also present.
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View more >In the structure of title compound, [Rb(C7H4NO5)(H2O)]n, the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO4 complex centres bridged by the carboxylate groups of the 5-nitrosalicylate ligands. The coordination about each Rb atom is completed by a monodentate water molecule and a phenolic O-atom donor which gives a bridging extension [Rb-O range = 3.116 (7)-3.135 (5) A ࠝ. The polymeric structure is stabilized by intermolecular water O- H...Ocarboxylate hydrogen bonds and weak inter-ring pi-pi interactions [minimum ring centroid separation = 3.620 (4) A ࠝ. An intramolecular O-H...O hydrogen bond between phenol and carboxylate groups is also present.
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Journal Title
Acta Crystallographica. Section E: Structure Reports Online
Volume
E67
Copyright Statement
© The Author(s) 2011. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Subject
Chemical sciences
Inorganic chemistry not elsewhere classified