Kinetic limitations in the Mg-Si-H system
Author(s)
Paskevicius, M
Sheppard, DA
Chaudhary, A-L
Webb, CJ
Gray, E MacA
Tian, HY
Peterson, VK
Buckley, CE
Year published
2011
Metadata
Show full item recordAbstract
Magnesium silicide (Mg2Si) has attracted interest as a hydrogen storage material due to favorable thermodynamics (DHdesorption 젳6 kJ/mol H2) for room temperature operation. To date, direct hydriding of Mg2Si under hydrogen gas to form MgH2 and Si has only been attempted at low pressure and has been hindered by poor kinetics of absorption. In this paper we study the dehydrogenation reaction with in-situ neutron powder diffraction and present results of our attempts to hydrogenate Mg2Si under both hydrogen and deuterium gas up to temperatures of 350 C and pressures of 1850 bar. Even under these extreme absorption conditions ...
View more >Magnesium silicide (Mg2Si) has attracted interest as a hydrogen storage material due to favorable thermodynamics (DHdesorption 젳6 kJ/mol H2) for room temperature operation. To date, direct hydriding of Mg2Si under hydrogen gas to form MgH2 and Si has only been attempted at low pressure and has been hindered by poor kinetics of absorption. In this paper we study the dehydrogenation reaction with in-situ neutron powder diffraction and present results of our attempts to hydrogenate Mg2Si under both hydrogen and deuterium gas up to temperatures of 350 C and pressures of 1850 bar. Even under these extreme absorption conditions Mg2Si does not absorb any measureable quantity of hydrogen or deuterium.
View less >
View more >Magnesium silicide (Mg2Si) has attracted interest as a hydrogen storage material due to favorable thermodynamics (DHdesorption 젳6 kJ/mol H2) for room temperature operation. To date, direct hydriding of Mg2Si under hydrogen gas to form MgH2 and Si has only been attempted at low pressure and has been hindered by poor kinetics of absorption. In this paper we study the dehydrogenation reaction with in-situ neutron powder diffraction and present results of our attempts to hydrogenate Mg2Si under both hydrogen and deuterium gas up to temperatures of 350 C and pressures of 1850 bar. Even under these extreme absorption conditions Mg2Si does not absorb any measureable quantity of hydrogen or deuterium.
View less >
Journal Title
International Journal of Hydrogen Energy
Volume
36
Issue
17
Subject
Chemical sciences
Engineering